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electrochemical cell
spontaneous, positive ecell, produces energy, exothermic
electrolytic cells
non-spontaneous, negative ecell, consuems energy, endothermic
cathode’s terminal in an electrochemical cell
positive
anode’s terminal in an electrochemical cell
negative
cathode’s terminal in an electrolytic cell
negative
anode’s terminal in an electrolytic cell
positive
overpotential effect
the voltage required for certain soutions is higher than the expected value
overpotential effect cause
slow reaction at the electrode requires extra voltage to speed up rate