3.3.4 Alkenes

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24 Terms

1

What is an alkene

Unsaturated hydrocarbon

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2

Define unsaturated

Containing a carbon-carbon double bond

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3

What makes C=C susceptible to an attack from electrophiles

They are an area of high electron density

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4

Define an electrophile

Electron acceptors that are attracted to areas of high electron density

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5

Give some examples of electrophiles

HBr, Br2, H2SO4

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6

What can be used to identify alkenes

Bromine water

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7

Describe a positive result of an alkenes test

Bromine water goes from orange-brown to colourless

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8

What can alkenes and electrophiles form

Halogenoalkanes

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9

What forms in electrophiles addition when the double bond is broken

A carbocation

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10

Define a carbocation

A carbon atom with only 3 bonds - so a positive charge

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11

How does carbocation’s stability affect its formation

More stable is more likely

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12

Which structures of carbocations is most and least stable

Tertiary is most, primary least

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13

Define the major product

The most stable possible

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14

Define addition polymers

Produced from alkenes where the double bond is broken to form a repeating unit

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15

How must a repeating unit be shown

With extended bonds through the brackets

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16

How can you give polymer chains different properties

By changing reaction conditions

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17

Why are polymers good as everyday plastic products

They have multiple strong, non-polar covalent bonds

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18

Why are polymers not biodegradable

Due to the unreactive nature of bonds

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19

PVC

An addition polymer with waterproof properties

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20

Why is PVC waterproof

Addition of plasticisers

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21

why do groups in unsaturated compounds remain fixed

there is no free rotation around the C=C

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22

what is the inductive effect

the carbons push electrons towards the carbocation making it less positively charged

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23

what occurs in all addition reactions

an electrophile reacts with double bond in alkenes

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24

what is the test for unsaturation

bromine water is shaken with the compound

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