ranking acids and conjugate bases rules fucking learn these bro.

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14 Terms

1
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what is the order used for ranking conjugate bases

C- charge

A- atom

R- resonance

I- induction

O- orbitals

2
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What does a negative charge do to the electrons around a nucleus

-raises the number of them

-electrons cant get close due to repulsion, so they end up spreading out (having a bigger electron cloud)

3
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What does a positive charge do to the electrons around a nucleus

-decreases number of electrons around nucleus, attracts electrons closer to nucleus

-lowers the energy and make it less reactive

4
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when is charge relevant…?

when comparing acids and their conjugate bases, or  vice versa

5
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When looking at atoms while comparing bases when does basicity increase?

as the atom gets smaller and less electronegative

6
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Smaller base makes a ______ bond to a proton (longer or shorter)

shorter (also stronger)

7
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Is a smaller base a stronger or weaker base?

Stronger base

8
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When going from R—>L within a same period, what are we concerned about for ranking basicity?

the electronegativity of atoms

9
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Is a less electronegative base a weaker or a stronger base?

stronger base and less stable base

10
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when looking at a same group, what are we concerned about for ranking basicity?

the size of atoms and stability of conjugate bases

11
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When comparing acids what should you do?

-always draw out the conjugate base!

-the weaker base will be the stronger acid!!

12
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Does resonance stabilize bases?

Yes, something without resonance will be less stable and therefore a stronger base.

13
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14
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