Electronegativity and Bond Polarity

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21 Terms

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Electronegativity

an atom's ability to attract shared electrons in a chemical bond

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What direction does electronegativity increase?

Left to Right across a period, and decreases going down a group

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What group has the highest electronegattivity?

Non-Metals

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Chemical Bond

an attractive force that holds atoms together. The type of bond formed depends on the electronegativity differencebetween the bonding atoms.

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The type of chemical bond formed depends on

the electronegativity difference between the bonding atoms.

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Non-Polar Covalent Bonds

Occurs between nonmetal atoms where electrons are shared equally or almost equally.

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What is the electronegativity difference between non-polar covalent bonds?

0-0.4

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Polar Covalent Bond

Occurs between nonmetal atoms where electrons are shared unequally.

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What is the electronegativity difference between polar covalent bonds?

0.5-1.8

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Polarity

Refers to the distribution of electrical charge around a molecule, resulting in a dipole moment due to differences in electronegativity between bonded atoms.

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Dipole

A molecule that has a positive and a negative end due to unequal distribution of electrons.

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What does this represent δ+?

Positive End

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What does this mean δ-?

Negative End

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What do the arrows in dipoles represent?

Point from positive end to negative end (direction of e-)

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Ionic Bond

Occurs between a metal and a nonmetal due to the transfer of electrons.

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What is the electronegativity difference of an Ionic Bond

1.8<

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Special Case of Bond

1.8-2

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What does the Polarity of Molecule depend on?

polarity of its individual bonds and its molecular geometry (shape).

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Do Polar or Non-Polar Molecules contain nonpolar bonds and polar bond that dipoles cancel out due to symmetrical arrangement.

Non-Polar Molecules

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Do Polar or Non-Polar Molecules contain polar bonds that dont’ cancel each other out?

Polar Molecules

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What element has the most electronegativity?

Fluorine (F)