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Are accidents involving pesticides more likely to occur while being transported or while sitting?
While being transported
IS it okay to carry pesticides in the passenger compartment of a vehicle?
NO - spilled chemicals and hazardous fumes can seriously injure the occupants. They are also almost impossible to remove completely from the vehicle's interior
What should you do if pesticides must be carried in a station wagon or other enclosed vehicle?
Ventilate the cargo and passenger compartments, roll down the windows
If there are any injuries, contamination, or damage resulting from a chemical release during transportation, who can be held accountable.
Both the owner and the operator
Components of making technical data for each pesticide.
emergency information and a copy of the MSDS is in the vehicle transporting the pesticides
Steps to take when transporting pesticides
-Inspect containers
-Make sure that labels are readable and securely attached,
-Handle containers carefully
-Use packing or shipping container
-use a secondary liner to protect floor and sides of cargo area
-Secure loads with ropes, brace bars or other appropriate devices
-Stabilize anything that could damage anything
-Place waterproof cover over load
-Never allow people, livestock or pets to ride with cargo
-Separate food, feed, seed, plants from pesticides
Does the DOT require diamond-shaped placards on vehicles that are transporting all pesticides?
only some pesticides require placards: some fertilizers, fuels, and explosives
What is the quantity that triggers the development of a transportation security plan?
Containers larger than 19 gallons or quantities greater than 1,000 pounds. OR MATERIALS THAT REQUIRE PLACARDS
For commercial applicators in PA, What are the setbacks for restricted use pesticide facilities from private wells and public water sources
100' private well and 100' public water source
Effects of moisture on pesticide containers
-Rusting of metal containers
-Splitting or crumbling of paper + cardboard containers
-Peeling, smearing that makes labels unreadable
-Release of active ingredients in slow-release products
Important qualities of a good facility
-controlled temperature
-air from facility with pesticides isn't directed anywhere else
-adequate lighting
-floor constructed of non-porous materials such as sealed cement and glazed ceramic tile
-store only pesticide containers and equipment in the storage facility
-Keep labels legible
If a label is damaged, you should write this information on the container.
-The common name of the active ingredient
-The percentage of each active ingredient
-The EPA registration number
-The signal word (Caution, Warning or Danger)
-The use classification (general or restricted-use)
Ways to keep containers stored safely
-Never use food or drink containers
-Keep containers securely closed when not in use
-Place large drums and heavy bags on plastic pallets
What is bulk storage?
Refers to commercial storage of any pesticide held in stationary pesticide containers designed to hold undivided quantities greater than 500 gallons of liquid pesticide or greater than 4,000 pounds of dry pesticide
How big should a dike be around a tank/pesticide area?
Large enough to contain the volume of the liquid in the tank plus 10%
What are some signs of pesticide deterioration to look for while mixing?
-Excessive clumping
-Poor suspension
-layering
-Abnormal coloring
Sometimes the first indication of pesticide deterioration may be poor pest control or damage to the treated crop or surface. Date of purchase should be marked on every container
Isolate waste products
Have a designated section for disposal or recycling and be sure to label all containers accordingly
how can you increase security and management of pesticides?
Risk assessment - to see what assets need to be protected
Employee training and security awareness
Secure buildings and surrounding property
Secure application equipment and vehicles
Protect confidential information
Develop procedures and policies that support security needs
Coordinate with authorities in a timely manner in terms of suspicious activity occuring
Which property of a pesticide would make it more likely to move in surface water runoff?
high solubility
Runoff and erosion are sources of what?
water contamination by pesticides
What is an example of nonpoint source contamination of groundwater
Pesticides that dissolve and leach through soil after it rains.
Under which conditions are pesticides more likely to leach through soil?
Sandy soil, low in organic matter
Which best management practice will help prevent contamination of surface water and groundwater by pesticides?
Following IPM principles
Which two factors are most important in avoiding vapor drift?
Temperature and pesticide volatility
Pesticide labels may list what around sensitive areas?
Special precautions
Persistence
the ability of a pesticide to remain present and active in its original form for an extended period of time.
Residue
pesticide that remains in the environment after application.
Volatility
the tendency of a pesticide to turn into a gas or vapor.
Runoff
surface movement off a treated site
Leaching
downward movement through soil.
Spray drift
the off
Temperature inversion
stable atmospheric conditions
When is drift most likely to occur over long distances?
temperature inversion.
Vapor drift
the movement of pesticides as gaseous vapors from the target area
Particle drift
the movement of solid particles from the target area in the air during or just after an application.
Point source pollution is what?
pollution that comes from a specific identifiable location.
Saturated zone
the layer of soil, sand, gravel, or fractured bedrock in which all available areas are filled with water.
Water table
the boundary between the saturated zone and the overlying unsaturated rock and soil.
Aquifer
the geologic formation from which groundwater can be drawn.
Factors affecting leaching
texture and structure, organic matter, depth to groundwater, and geology.
Permeability
allow water and dissolved pesticides to move freely downward.
Placards
diamond-shaped signs to be placed on vehicles that transport certain types of quantities of hazardous materials.
Transportation security plan
a risk assessment, background checks, unauthorized access prevention, en-route security measures, training, designated senior official, all documented in writing and reviewed annually.
What offers the greatest protection during transportation?
Enclosed and lockable cargo boxes
What should you consider when selecting a storage site?
terrain
What is the first thing you should do if a pesticide container is leaking?
Put on PPE
What recommended practice will minimize pesticide storage problems?
Store metal pesticide containers on the higher shelves to prevent rusting
What is the first step a business should take to develop an effective pesticide security program
Conduct a risk assessment of business vulnerabilities.
What is considered a good security practice?
Instruct employees on pesticide inventory control
What is important to do during emergency response planning?
Make a detailed report of what took place before, during, and after the incident.
What is the backbone of any emergency response plan?
outlining the sequence of actions to take in a crisis.
What will further reduce the risk of a pesticide fire?
Keep a fire detection system in the storage area.
What is a recommended action to take in the event of a pesticide fire?
Construct berms to contain contaminated runoff water.
What is an appropriate action to take in the event of a pesticide spill? Put on PPE before responding to the spill.