topic 5 - separate chemistry 1

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state what most metals are known as

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1

state what most metals are known as

transition metals

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2

state the properties of transition metals

  • high melting/boiling point

  • high density

  • they form coloured compounds

  • catalysts of metals and their compounds

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3

state what the oxidation of iron causes

corrosion

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4

state the definition of corrosion

  • the gradual destruction of metal

  • due to chemical reactions between metals, oxygen and water

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5

explain how the exclusion of oxygen can prevent iron rusting

  • rusting is the reaction of oxygen, water and metal together

  • to form iron oxide

  • without oxygen, this reaction cannot take place

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6

explain how the exclusion of water can prevent iron rusting

  • rusting is the reaction of oxygen, water and metal together

  • to form iron oxide

  • without water, this reaction cannot take place

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7

explain how sacrificial protection can prevent iron rusting

  • when iron is galvanised with a metal of a higher reactivity

  • the iron is protected from water and oxygen by a physical barrier

  • although reactions will take place with the galvanised metal, oxygen and water

  • the iron will remain unreacted

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8

state what electroplating is

  • process where

  • the surface of one metal

  • is coated with the layer

  • of a different metal

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9

explain how electroplating can be used to improve the appearance of metal objects

  • electroplating allows a metal object to be coated in a layer of another metal

  • this coating could improve the appearance of the metal object

  • e.g. silver plating cutlery and jewellery

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10

explain how electroplating can be used to improve the resistance to corrosion of metal objects

  • electroplating allows a metal object to be coated in a layer of another metal

  • this coating is usually a metal with higher reactivity than the metal object

  • this mean the metal coating will react with oxygen and water and corrode

  • meaning the metal object is physically protected from the oxygen and water

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11

state what a metal alloy is

  • where metals are physically mixed together

  • but not chemically combined

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12

explain why converting metal into alloys increases the strength of the product

  • alloys often have properties that differ to the pure metal

  • alloys contain atoms of different sizes that disrupt the regular arrangement of atoms

  • this makes it harder for the layers of metal atoms to slide over each other

  • making the alloy harder than the pure metal

  • thus making it stronger

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13

explain why iron is alloyed with other metals to produce alloy steels

  • cast iron from a furnace is 96% iron

  • with carbon, phosphorus, silicon and sulfur impurities

  • cast iron is too brittle for many common uses

  • so it is alloyed to make steel by removing some of the impurities

  • where it can then be used for actions such as construction, transport and manufacturing

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14

explain how the uses of aluminium as foil is related to its properties

  • used in domestic food wrapping/storing food

  • as it has a low reactivity

  • and is very malleable

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15

state what the magnalium alloy is made of

  • magnesium

  • aluminium

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16

explain how the uses of magnalium in aircraft parts is related to its properties

  • magnalium is low density

  • and corrosion resistant

  • meaning it is a safe material to use in aircrafts

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17

explain how the use of copper in electrical wirings is related to its properties

  • copper is corrosion resistant

  • and an electrical conductor

  • making it a safe material to use in the wirings

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18

state what brass is made of

  • copper

  • zinc

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19

explain how the use of brass in pins for electrical plugs is related to its properties

  • brass is stronger than copper

  • and is also an electrical conductor

  • making it a good material to use in the pins

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20

state what jewellery gold is made of

  • gold

  • copper

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21

explain how the use of jewellery gold in in jewellery is related to its properties

  • the gold alloy allows the jewellery to stay strong

  • whilst still remaining shiny

  • and corrosion resistant

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22

state the equation to find concentration in mol/dm³

concentration (mol/dm³) = no. of moles (mol) / volume (dm³)

<p>concentration (mol/dm³) = no. of moles (mol) / volume (dm³)</p>
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23

state the equation to convert concentration in mol/dm³ to g/dm³

g/dm³ = mol/dm³ x Mr

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24

state the equation to convert concentration in g/dm³ to mol/dm³

mol/dm³ = g/dm³ / Mr

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25

state the method of how to carry out an acid-alkali titration

  1. use pipette and pipette filler to place 25cm³ of NaOH solution into the conical flask

  2. place the conical flask on a white tile so the tip of the burette is inside the flask

  3. add a few drops of suitable indicator to the conical flask

  4. perform a rough titration by taking an initial burette reading, while swirling the flask

  5. quickly close the tap when a sharp colour change occurs and record the final volume at eye level

  6. repeat the titration with a fresh flask of NaOH solution

  7. at the rough end volume, add the solution from the burette one drop at a time until the indicator just changes colour

  8. record the volume to the nearest 0.5cm³

  9. repeat until 2 concordant results are achieved

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26

explain how to use titration results to carry out simple calculations

  1. write out the balanced reaction of the neutralisation reaction

  2. calculate the moles of the known solution given the volume and concentration

  3. use the equation to deduce the moles of the unknown solution

  4. use the moles and the volume of the unknown solution to calculate the concentration

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27

state the equation to find percentage yield

% yield = (actual yield / theoretical yield) x 100

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28

state what actual yield is

  • the yield of a reaction

  • that is usually less than the calculated theoretical yield

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29

state what causes the actual yield of a reaction to be less than the theoretical yield

  • incomplete reactions

  • practical losses during the experiment

  • competing, unwanted reaction

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30

state what atom economy is

  • studies the amount of reactants that get turned into useful products

  • it’s used to analyse the efficiency of reactions

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31

state the equation to find atom economy

atom economy = (Mr of desired products / Mr of all reactants) x 100

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32

explain why a particular pathway in a reaction is chosen to produce a specified product using atom economy

  • reactions that have low atom economies use up a lot of resources

  • and produce excess waste material

  • which needs to be disposed of

  • making it an expensive procedure

  • these reactions are unsustainable as they aren’t economically attractive

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33

explain why a particular pathway in a reaction is chosen to produce a specified product using yield

  • high yield rates are desirable attributes of chemical reactions

  • as they produce less waste products

  • therefore improving the efficiency of the reaction

  • making the reaction more economically-attractive

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34

explain why a particular pathway in a reaction is chosen to produce a specified product using equilibrium position

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