electrophilic aromatic substitution activating/deactivating groups - orgo 1

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9 Terms

1
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very strongly activating grs + effect on orientation (4)

ortho/para directing

<p>ortho/para directing</p>
2
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strongly activating + orientation effect (3)

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3
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activating + orientation effect (3)

ortho/para

<p>ortho/para</p>
4
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weakly deactivating + orientation effect (2)

ortho/para directing

<p>ortho/para directing</p>
5
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strongly deactivating + orientation effect (4)

meta

<p>meta</p>
6
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very strongly deactivating + orientation effect

meta

<p>meta</p>
7
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conditions for aromaticity

  • planar

  • conjugated (needs to be p-orbitals present so no sp3 carbons)

  • cyclic 

  • follows huckel’s rule: contains 4n + 2 pi electrons

8
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conditions for antiaromaticity

  • follows all aromaticity rules

  • has only 4n pi electrons

9
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conditions non aromaticity

  • as soon as it disobeys one of the conditions for aromaticity and/or non-aromaticity