Particle Theory
Matter is made of particles that are in constant motion based on the amount of energy they have
more dense water less dense water
sinks rises
covalent bond
when 2 atoms share a pair of electrons (in their outer shell) (strongest bonds)
ionic bond
bond where there is an attraction between 2 oppositely charged ions
covalent bond
when two atoms share a pair of electrons (in their outer shell) (strongest bond)
hydrogen bond
a relatively weak bond formed between molecules containing a hydrogen atom bonded to an oxygen, nitrogen, or fluorine atom
sodium chloride
NaCl
calcium carbonate
CaCO3
magnesium sulfate
MgSO4
Chemical composition of water
Local changes occur due to:
Volcanic Activity
runoff
atmospheric dissolution
what causes mixing in the ocean?
strong wind/wave action (storms)
currents
upwellings
cold surface water sinking
What makes density of water
· Water is less dense as a solid than it is as a liquid · This happens because the hydrogen bonds in ice are stable and at a fixed distance, keeping the water molecules further apart.
Explain how temperature gradients form
Differences in salinity
Warm water above cold water
lower salinity above higher salinity
do not mix
why Oxygen is less soluble than in freshwater?
explanation: higher salinities (so higher TDS) in water leaves less space for gases to "fit" into
Precipitation
dilutes sea water, decreases salinity
places especially affected: estuaries and near glaciers
Particle Theory
Matter is made up of tiny particles which are constantly moving.
covalent bond
A chemical bond that involves sharing a pair of electrons in their outer shell
ionic bond
A chemical bond resulting from the attraction between oppositely charged ions.
Evaporation
salt stays in solution, salinity increases
What affects salinity?
wind, but only from surface to ~200m deep
Currents
Temperature changes
Diffusion
Movement of molecules from an area of higher concentration to an area of lower concentration.
Density
As salinity increases, density increases
Lower salinity (and lower density) water on top of higher salinity (and higher density) water
As temperature increases
density decreases
atmospheric pressure
more oxygen will dissolve when pressure is increased -oxygen in atmosphere is "forced" into ocean by pressure
water pressure
the greater the depth of water the greater the pressure which causes increases oxygen dissolution
pressure "forces" oxygen into the water
As depth increases...
DO decreases
DO can become saturated when
photosynthesis
turbulence caused by waves
most DO at the surface
DO can decrease by
respiration
increase in temperature
vampire squid
threatened by decreasing oxygen doesnt move due to little oxygen
Jubillee
upwelling of oxygen-poor bottom waters force fish from deep water of mobile bay to shallower coaster areas
salinity increases
density increases
Warm and cold water don't mix well. Why?
forms temperature gradients
warm water sits on top of cold water
Dissolved Oxygen (explain)
high concentration at the surface layer due to turbulence and photosynthesis
extremely low concentration below the surface layer due to respiration but lack of turbulence and photosynthesis (no light)
increase in deeper water due to few organisms respirating but increases dissolution as a result of high pressure and cold water
Dissolved Oxygen (describe)
high concentration of DO at the surface
Then it decreases rapidly as depth increases
Then it increases rapidly as depth increases before becoming constant
cold water can dissolve more oxygen than warm water. Why?
explanation: warmer water has more (kinetic) energy and the molecules move faster which causes molecules to evaporate quickly
atmospheric dissolution
dissolved gases remain at equilibrium (mostly) with atmosphere
concentrations depend on relative solubility, temperature, pressure, and salinity of the ocean
runoff
-flow of water from land to ocean
drains to oceans directly from rivers
volcanic activity
-Submerged volcanoes release gases, including chlorine
major source of chloride ions
dissolve in atmospheric h2o -enter ocean by precipitation
Volcanic activity gases
CO2, SO2, H2S, HCI
Hydrogen bonds and water
in water, oxygen atom has a negative charge, hydrogen atoms have a positive charge
Designing an experiment
determine the IV and range of values
Determine the control variables
Determine how to keep control variables the same
Decide on the number of replicates
Determine the timeframe
Determine the measurements that will be taken