Alkene Addition Reactions
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11 Terms
1
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HX (Hydrohogenation)
Markovnikov (H&X)
2
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HBr, ROOR (Radical Addtion of HBr)
Anti-Markovnikov (H&Br)
3
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H3O+ or [H2SO4] (Acid Catalyzed Hydration)
Markovnikov (H&OH)
4
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1)Hg(OAc)2, H2O 2) NaBH4 (Oxymercuration-Dermercuration)
Markovnikov (H&OH)
5
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1)BH3 • THF 2) H2O2, NaOH (Hydroboration-Oxidation)
Anti-Markovnikov (H&OH) Syn
6
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H2, Pt (Catalytic Hydrogenation)
(H&OH) Syn
7
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Br2 or Cl2 (Bromination or Chlorination)
(Br&Br) or (Cl&Cl) Anti
8
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Br2, H2O (Halohudrin Formation)
OH to more substituted group (Br&OH) Anti
9
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KMnO4 or OsO4 / NMO (Syn Dihydroxlyation)
(OH&OH) Syn
10
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RCO3H (MCPBA) (Epoxidation)
(Epoxide) Anti
11
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1) O3 2) DMS or Zn/H2O
(Cleave C=C, form two C=O groups)
Note 
Flashcards (24)