Gen. Chem. II Lecture 25: Common Ion & Buffers

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Flashcards covering key concepts from the chemistry lecture on common ions and buffers, including definitions, calculations, and applications.

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1
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What is the Common Ion Effect?

The Common Ion Effect refers to the impact on the pH of a weak acid or base ionization caused by the addition of a salt containing the same ion formed during ionization.

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How does the addition of a common ion affect equilibrium?

The addition of a product ion pushes the ionization equilibrium towards the reactants, causing a decrease in [H3O+] and an increase in pH.

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What is the Ka value for formic acid (HCOOH)?

Ka for formic acid is 1.8 x 10^-4.

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What are buffers?

Buffers are solutions that resist changes in pH when an acid or base is added.

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What is the typical pH range of blood?

The pH of blood is typically between 7.35 and 7.45.

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What determines the pH of a buffer?

The pH of a buffer can be calculated using the Henderson-Hasselbalch equation: pH = pKa + log([Con Base]/[Acid]).

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What is Buffer Capacity?

Buffer capacity is the amount of acid or base a buffer can consume before experiencing significant pH change.

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What are the components in a buffer solution?

A buffer solution typically contains a weak acid and its conjugate base or a weak base and its conjugate acid.

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How do you calculate the pH when mixing two solutions to create a buffer?

You determine concentrations after dilution and then apply the Henderson-Hasselbalch equation.

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Which acid/base mixture would be best for a buffer with pH=3.50?

Formic acid with formate (Ka= 1.8x10^-4) is a suitable choice for a buffer with pH=3.50.