Types of Donors (Inorganic Chem)

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5 Terms

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Sigma Only

Uses only sigma interactions (no pi, no d-orbitals, no extra lone pairs)

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Pi Donor

Ligands with filled p-orbitals or pi type orbitals (extra lone pairs)

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Pi Acceptor

Ligands with an empty pi* or d-orbitals (double or triple bond,

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Pi Donor Effect of t2g

Raises t2g, stabilizes t2g, smaller delta o

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Pi Acceptor Effect on t2g

Lowers t2g, destabilizes t2g, greater delta o