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0th order rate law
rate = k; units: mol/L*s
1st order rate law
rate = k[A]; units: 1/s
2nd order rate law
rate = k[A][B]; units: L/mol*s
0th order integrated rate law
[A]final = -kt + [A]initial
1st order integrated rate law

2nd order integrated rate law

0th order half-life

1st order half-life

2nd order half-life

1st order graph
ln[A] vs time
![<p>ln[A] vs time</p>](https://knowt-user-attachments.s3.amazonaws.com/a9912415-eb64-4b1d-84cb-6b6ff5820d0f.png)
2nd order graph
1/[A] vs time
![<p>1/[A] vs time</p>](https://knowt-user-attachments.s3.amazonaws.com/cd4979e5-55cb-49ad-aea9-e957ec397f8b.png)
0 order graph
[A] vs time
![<p>[A] vs time</p>](https://knowt-user-attachments.s3.amazonaws.com/e79e3d68-6d14-4065-81c2-b4422c231688.jpg)
1st order half life is
constant
2nd order half life is
NOT constant, each successive half life doubles
0 order half life is
NOT constant, each successive half life is 1/2