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WHMIS
Workplace Hazardous Materials Information System
Purpose of WHMIS
Protect workers by giving standardized information on hazards
SDS or MSDS (Safety Data Sheet)
Detailed document for each hazardous product giving composition
Flame pictogram
Indicates flammable gases
Flame over circle pictogram
Indicates oxidizing substances that can cause or intensify fire.
Exploding bomb pictogram
Indicates explosives
Gas cylinder pictogram
Indicates compressed
Corrosion pictogram
Indicates corrosive to metals and causes severe skin burns and eye damage.
Skull and crossbones pictogram
Indicates acute toxicity that can be fatal or toxic even in small amounts.
Health hazard pictogram
Indicates long-term health effects like carcinogen
Exclamation mark pictogram
Indicates irritant
Environment pictogram
Indicates aquatic environmental toxicity (not mandatory in WHMIS 2015).
Classroom safety: eye and hair
Always wear goggles and tie back long hair during lab activities.
Classroom safety: food and drink
Do not eat or drink in the lab and never taste chemicals.
Classroom safety: instructions
Read all instructions before starting and follow teacher directions exactly.
Classroom safety: spills and injuries
Report all spills
Classroom safety: disposal
Dispose of chemicals only as instructed
Household hazard shapes
Octagon means danger
Household hazard pictures
Explosive
Physical change
Change in state
Examples of physical change
Ice melting
Chemical change
Change where new substances with different properties form because atoms rearrange.
Examples of chemical change
Iron rusting
Indicator: colour change
Colour changes in a way that is not just dilution
Indicator: gas produced
Formation of bubbles
Indicator: precipitate
Formation of a solid in a solution that was previously clear.
Indicator: energy change
Temperature increase or decrease
Exothermic reaction
A reaction that releases energy to the surroundings and usually feels warm or hot.
Exothermic energy placement
Energy is on the product side of the chemical equation and surroundings’ temperature increases.
Exothermic examples
Combustion of fuels
Endothermic reaction
A reaction that absorbs energy from the surroundings and often feels cold.
Endothermic energy placement
Energy is on the reactant side of the chemical equation and surroundings’ temperature decreases.
Endothermic examples
Photosynthesis
Reaction rate: temperature
Higher temperature makes particles move faster
Reaction rate: concentration
Higher concentration means more particles in the same volume and more collisions.
Reaction rate: surface area
Smaller pieces or powders have more exposed surface area
Reaction rate: catalyst
A substance that speeds up a reaction by lowering activation energy without being used up.
Atomic number
Number of protons in an atom
Period on periodic table
A horizontal row where elements have the same number of occupied electron shells.
Group or family
A vertical column where elements have similar chemical properties and the same number of valence electrons.
Group 1: alkali metals
Very reactive metals with 1 valence electron and a common charge of +1.
Group 2: alkaline earth metals
Reactive metals with 2 valence electrons and a common charge of +2.
Transition metals
Groups 3–12
Group 17: halogens
Very reactive nonmetals with 7 valence electrons and a common charge of −1.
Group 18: noble gases
Very unreactive gases with full valence shells
Metals
Elements that are usually shiny
Nonmetals
Elements that are often dull
Metalloids
Elements along the staircase that have properties between metals and nonmetals (such as silicon and germanium).
Common charge: Group 1
Form +1 ions like Na⁺ and K⁺.
Common charge: Group 2
Form +2 ions like Ca²⁺ and Mg²⁺.
Common charge: Group 13
Form +3 ions like Al³⁺.
Common charge: Group 16
Form −2 ions like O²⁻ and S²⁻.
Common charge: Group 17
Form −1 ions like Cl⁻
Diatomic elements list
Elements that exist as X₂ when pure: H₂
Protons in an atom
Number of protons equals the atomic number of the element.
Electrons in a neutral atom
In a neutral atom
Neutrons in an atom
Neutrons equal the mass number minus the atomic number.
Example: carbon-12
Atomic number 6 → 6 protons and 6 electrons
mass number 12 → 6 neutrons.
Example: sodium-23
Atomic number 11 → 11 protons and 11 electrons
mass number 23 → 12 neutrons.
Steps for molecular (molar) mass
Count atoms of each element
Example: water molar mass
For H₂O
Ionic compound definition
Compound formed by electron transfer between metal and nonmetal (or polyatomic ions) creating cations and anions.
Ionic compound properties
High melting points
Molecular compound definition
Compound formed when nonmetals share electrons
Molecular compound properties
Oftentimes lower melting points and many are gases or liquids at room temperature.
Recognizing ionic from formula
If the formula starts with a metal or NH₄⁺
Recognizing molecular from name
If the name uses Greek prefixes like mono-
Naming simple ionic compounds
Name the metal first and change the nonmetal ending to “-ide” (for example
Naming ionic with polyatomic ions
Keep the polyatomic ion name such as sulfate
Transition metal naming
Determine the metal’s charge and show it with a Roman numeral in brackets (for example
Example FeCl₂ name
Two Cl⁻ (−2 total) means Fe must be +2
Example FeCl₃ name
Three Cl⁻ (−3 total) means Fe must be +3
Naming molecular compounds
Use Greek prefixes to show the number of atoms and end the second element with “-ide.”
Common prefixes list
Mono-
Molecular name example: CO
Carbon monoxide (not “monocarbon monoxide”).
Molecular name example: CO₂
Carbon dioxide.
Molecular name example: N₂O₄
Dinitrogen tetroxide.
Writing ionic formulas
Write charges for cation and anion
Example: magnesium chloride formula
Mg²⁺ and Cl⁻ combine as MgCl₂ because two Cl⁻ balance +2.
Example: aluminum oxide formula
Al³⁺ and O²⁻ form Al₂O₃ so that total charge is zero.
Polyatomic ion in formulas
Use brackets when more than one polyatomic ion is needed
Writing molecular formulas from names
Use the prefixes as subscripts
Example: sulfur trioxide formula
Sulfur trioxide is SO₃.
Example: carbon tetrachloride formula
Carbon tetrachloride is CCl₄.
Law of Conservation of Mass
In a chemical reaction matter is not created or destroyed and total mass of reactants equals total mass of products.
Balancing equations rule
Only change coefficients
Coefficient meaning in equations
A coefficient multiplies all atoms in the formula
General balancing strategy
Balance metals first
Balancing example Fe + O₂
Balanced equation is 4Fe + 3O₂ → 2Fe₂O₃ with equal Fe and O atoms on both sides.
Acid properties
Acids taste sour
Acid formula patterns
Acid formulas usually start with H or end with COOH in many organic acids.
Base properties
Bases taste bitter
Base formula patterns
Bases often contain OH⁻ such as NaOH or KOH or are metal oxides and hydroxides.
pH scale description
Scale from 0 to 14 measuring how acidic or basic a solution is.
Neutral pH value
Neutral solutions like pure water have a pH of 7.
Acidic pH range
Acidic solutions have pH less than 7
Basic pH range
Basic solutions have pH greater than 7
Strength ranges on pH scale
pH 0–3 strong acids