biomolecules

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acetic acid

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Description and Tags

organic; ratofy.

20 Terms

1

acetic acid

(CH3COOH); carbohydrate exception; same gen formula

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2

rhamnose

C6H12O5; carbohydrate. diff formula

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3

sucrose

common; present in homes

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4

lactose

milk

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5

monosaccharides

glucose, fructose, ribose.

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6

sucrose(hydrolysis)

glucose+fructose

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7

maltose(hydrolysis)

glucose+glucose

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8

polysaccharides

starch, cellulose, glycogen, gums, etc.

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9

non sugars

polysaccharrides, not sweet

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10

fact about monosaccharides

reducing

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11

condition for reucing sugar: disac

free aldehydic or ketonic group; maltose or lactose

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12

non reducing disac

sucrose

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13

prep of glucose (i)

from sucrose; boiling; h2so4 or dil HCl; gives glucose+fructose

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14

commercial method

obtained by hydrolysis of starch OR cellulose by boiling it with dilute H2SO4 at 393 K under pressure 2-3 atm.

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15

aldohexose

dextrose; glucose

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16

structure; heating

On prolonged heating with HI, it forms n-hexane, suggesting that all the six carbon atoms are linked in a straight chain.

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17

Cyclic Structure of Glucose

Schiffs test; NaHSO3

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18

cyclic structure

The pentaacetate of glucose does not react with hydroxylamine indicating the absence of free —CHO group.

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19

alpha glucose

The α-form of glucose (m.p. 419 K) is obtained by crystallisation from concentrated solution of glucose at 303 K

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20

beta glucose

(m.p. 423 K) is obtained by crystallisation from hot and saturated aqueous solution at 371 K.

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