reacting alkanes to halogens

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10 Terms

1
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What are the conditions for a halogen to react to an alkane

UV light to provide activation energy for the reaction, reaction is a substitution of a hydrogen and halogen

2
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What does unequal splitting produce

Releases ions, process is known as heterolysis or heterolytic fission

3
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What does equal splitting produce

Radicals, process known as homolysis or homolytic fission

4
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What is the name of the reaction

Free radical substitution

5
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What are the 3 stages

Initiation, propagation and terminatin

6
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What happens in initiation

UV light breaks the Cl-Cl bond byhomolytic fission to give 2 chlorine radicals, unpaired electron makes Cl reactive

7
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What happens in propagation

Chlorine radical attacks a methane molecule in substitution to form HCl and a methyl radical

8
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What happens after the methyl radical forms

It attaches a different chlorine molecule, this cycle of propagation continues until the reagents are used up

9
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What happens in termination

2 radicals join to form a stable covalent bond

10
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What are the limitations of this

Substitution can continue happening to produce a variety of products and substitution can happen wherever in the carbon chain