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Hydrologic Cycle
The continuous movement and transformation of water molecules between liquid, vapor, and solid states
Evaporation
Process where water molecules escape from liquid to vapor phase
Condensation
Process where water vapor molecules return to liquid phase
Saturation
State where the number of evaporating molecules equals the number condensing
Absolute Humidity
Mass of water vapor per volume of air (g/m³); represents vapor density
Specific Humidity
Ratio of mass of water vapor to total mass of air (g/kg)
Mixing Ratio
Ratio of mass of water vapor to mass of dry air (g/kg)
Vapor Pressure
Partial pressure exerted by water vapor molecules in the air
Actual Vapor Pressure
The vapor pressure currently present in the air
Saturation Vapor Pressure
The vapor pressure when air is saturated at a given temperature
Relative Humidity (RH)
Ratio of actual vapor pressure to saturation vapor pressure, expressed as a percentage
Dew Point Temperature
Temperature to which air must be cooled (at constant pressure) to reach saturation
Supersaturation
Condition where RH exceeds 100%
Psychrometer
Instrument with wet-bulb and dry-bulb thermometers to measure humidity
Wet-Bulb Temperature
Lowest temperature reached by evaporating water into air
Wet-Bulb Depression
Difference between dry-bulb and wet-bulb temperatures
Hygrometer
General term for instruments measuring humidity
Hair Hygrometer
Uses human/horse hair that lengthens with increasing RH
Electrical Hygrometer
Measures humidity via changes in electrical resistance
Infrared Hygrometer
Measures IR energy absorbed by water vapor
Dew-Point Hygrometer
Cools a mirror to detect condensation and measure dew point
Condensation Nuclei
Tiny particles (e.g., dust, salt) that serve as surfaces for condensation
Hygroscopic Nuclei
"Water-seeking" particles that attract water vapor (e.g., salt, acid)
Hydrophobic Nuclei
"Water-repelling" particles that resist condensation (e.g., oils, waxes)
Dry Haze
Suspended particles that scatter light without condensation; appears yellowish or bluish
Wet Haze
Particles with condensed water that scatter light efficiently; reduces visibility
Fog
Cloud at ground level with visibility <1 km; formed by cooling or evaporation/mixing
Radiation Fog
Forms due to radiational cooling on clear, calm nights; also called ground or valley fog
Advection Fog
Forms when warm, moist air moves over a cooler surface
Upslope Fog
Forms when moist air ascends and cools adiabatically over elevated terrain
Evaporation (Mixing) Fog
Forms by mixing two unsaturated air masses
Steam Fog
Type of evaporation fog when cold air moves over warm water
Precipitation/Frontal Fog
Forms when warm rain evaporates into cold, moist air near the surface
Heat Index
Combines temperature and RH to estimate apparent temperature and human discomfort
Boiling Point
Temperature where saturation vapor pressure equals atmospheric pressure
Dalton’s Law
Total air pressure equals sum of partial pressures of individual gases
Phase Change
Transformation between solid, liquid, and gas states of water
Transpiration
Release of water vapor from plants into the atmosphere
Interception
Capture of precipitation by vegetation before reaching the ground
Percolation
Movement of water through soil and rock layers
Groundwater
Water stored underground in aquifers
Runoff
Surface water flow into streams, rivers, and oceans
Spatial Humidity Variation
Specific humidity highest in tropics, decreasing toward poles
RH Diurnal Variation
RH highest at night (cooler temps), lowest in afternoon (warmer temps)
Human Discomfort
High RH reduces evaporative cooling, increasing perceived temperature
Heat Cramps
Muscle spasms due to loss of water and salt from sweating
Heat Exhaustion
Fatigue, headache, nausea from prolonged heat exposure
Heatstroke
Life-threatening condition with body temperature >41°C; circulatory failure
Density of Humid Air
Humid air is less dense than dry air due to lighter water vapor molecules
Valley Fog
Radiation fog that forms in low-lying areas due to cold air drainage
Clear Night Condition
Promotes rapid cooling and dew/fog formation due to lack of cloud cover
Calm Night Condition
Allows coldest air to remain at ground level, aiding condensation
Light Breeze
Enhances radiation fog by bringing more moist air into contact with cold surfaces
Strong Breeze
Prevents radiation fog by mixing moist surface air with drier air above
Coastal Advection Fog
Forms when warm ocean air moves over colder coastal waters
Example RH Calculation
For T=30°C, Td=15°C: es=42 mb, e=18 mb, RH=42.9%
Example Dew Point Calculation
For T=32°C, RH=60%: es=47 mb, e=28.2 mb, Td=23°C
Frozen Dew
Dew that freezes when surface temperature drops below 0°C
Cloud Droplet Formation
Billions of vapor molecules condensing onto nuclei to form tiny droplets
Pollution and Nuclei
Highly polluted air can contain over 1 million nuclei per cm³
Haze Color Appearance
Dry haze appears yellowish against light backgrounds, bluish against dark
Visibility Reduction
Wet haze and fog significantly reduce visibility, especially in mornings
Boiling at High Elevations
Water boils at lower temperatures due to reduced atmospheric pressure
Cooking at High Elevations
Requires longer time due to lower boiling point of water
Radiosonde
Instrument package including electrical hygrometer, used for atmospheric sounding
Carbon Film Sensor
Used in electrical hygrometers; resistance changes with humidity
Mirror Cooling Method
Dew-point hygrometer detects condensation on a chilled mirror surface
Nighttime Cooling
Rapid cooling on clear nights leads to dew and fog formation
Adiabatic Cooling
Cooling of air as it rises and expands, leading to cloud/fog formation
Evaporative Cooling
Cooling effect when water evaporates, used in wet-bulb thermometer
Salt Particles as Nuclei
Hygroscopic nuclei like salt allow condensation at RH <100%
Oil Particles as Nuclei
Hydrophobic nuclei like oil resist condensation even at RH >100%
Formation of Dew
Occurs when surfaces cool below dew point, causing vapor to condense
Formation of Frost
Occurs when surfaces cool below freezing point, depositing ice crystals
Heat and Evaporation
Warm water evaporates more readily than cool water
Wind and Evaporation
Wind enhances evaporation by removing saturated air near surface
Saturation and Temperature
Warmer air requires more vapor molecules to reach saturation
Ice vs. Water SVP
Saturation vapor pressure is lower over ice than over liquid water
Binding Effect of Solutes
Dissolved salts reduce evaporation by binding water molecules
Body Cooling Mechanism
Evaporation of sweat is primary cooling method in warm weather
Low RH Comfort
Low RH allows rapid sweat evaporation, feels cooler than actual temperature
High RH Discomfort
High RH hinders evaporation, feels warmer than actual temperature
Water Vapor Weight
Water vapor molecules are lighter than nitrogen or oxygen molecules
Lifting of Humid Air
Less dense humid air rises more easily, leading to cloud formation
Precipitation Formation
Rising humid air cools, condenses, and forms precipitable droplets
Industrial Cities and Haze
High concentration of nuclei in polluted air leads to persistent haze
Nighttime Haze Transition
Dry haze transitions to wet haze as RH increases overnight
Fog Classification
Categorized by formation mechanism: radiation, advection, upslope, evaporation
Valley Collection of Cold Air
Cold, dense air flows downhill and collects in valleys, forming fog
Mixing of Air Masses
Combining unsaturated air masses can lead to saturation and fog
Warm Rain Evaporation
Rain falling through cold air evaporates and raises dew point, causing fog
Steam Fog Appearance
Rising condensate resembles steam, often over lakes or rivers in cold conditions
Frontal Fog Formation
Associated with weather fronts where warm and cold air masses meet
Health Risks of High Heat
Includes cramps, exhaustion, and stroke due to impaired cooling
Heat Index Chart
Used to determine apparent temperature based on T and RH
Importance of Dew Point
Better indicator of actual moisture content than relative humidity
Use of Psychrometric Charts
Graphs to determine RH, mixing ratio from wet/dry-bulb temperatures
Role of Nuclei in Condensation
Essential for condensation to occur at realistic humidity levels
Impact of Humidity on Density Explains why humid air rises and influences weather patterns
Nighttime Radiation Loss
Clear skies allow maximum IR radiation loss, cooling the surface