Arrhenius equation

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9 Terms

1
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What is the Arrhenius equation?

box) shows how the rate constant (k) varies with temperature (T)) and activation energy

(Ea) the minimum amount of kinetic energy particles need to react).

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What is the equation ?

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The rate constant and activation energy

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As the activation energy, Ea  gets bigger what happens to rate constant ? 

As the activation energy, Ea gets bigger, Rate constant gets smaller. 

Few reactant particles will have sufficient energy to react in a reaction with a high activation energy. Therefore, the reaction will only occur in a small number of collisions and at a slow rate.

<p>As the activation energy, Ea gets bigger, Rate constant gets smaller.&nbsp;</p><p></p><p>Few reactant particles will have sufficient energy to react in a reaction with a high activation energy. Therefore, the reaction will only occur in a small number of collisions and at a slow rate.</p>
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The rate constant and temperature

The equation also shows that as the temperature rises, k increases.

Higher temperatures

mean reactant particles move around faster and with more energy so they're more likely to collide and more likely to collide with at least the activation energy, so the reaction rate is higher.

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re-arrange to find Ea

Ea= (In (A) - In (k)) x RT

A=) Arrhenius constant

k) rate constant 

<p>Ea= (In (A) - In (k)) x RT</p><p></p><p>A=)&nbsp;Arrhenius constant </p><p></p><p>k) rate constant&nbsp;</p>
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re-arrange to find temperature

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Arrhenius Plot using y = mx+c

m = Ea/ R

x = 1/t c

c = Arrhenius constant

<p>m = Ea/ R </p><p></p><p>x = 1/t c</p><p></p><p>c =  Arrhenius constant </p>
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