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Adenosine Triphosphate (ATP)
a compound produced and used in living systems because it holds potential energy in its bonded phosphate groups
What happens when ATP interacts with another molecule?
it transfers a phosphate group to the other molecule. This destabilizes the other molecule allowing work to be done.
Phosphorylation
the transfer of the 3rd phosphate group of ATP to another molecule allows for the performing of chemical, mechanical, or transport work.
Which phosphate group is lost during phosphorylation?
The last group or 3rd group
How is ATP made?
ADP + Pi → ATP
How is ATP used?
ATP → ADP + Pi
...with the help of enzymes
and electrochemical
gradients
Substrate level phosphorylation of ADP to ATP
With the use of an enzyme, individual ADP molecules are phosphorylated back to ATP.
One at a time!
Oxidative phosphorylation of ADP to ATP
With the use of an enzyme called ATP synthase, an electrochemical gradient across a membrane draws protons near the ATP synthase. The spinning of ATP synthase phosphorylates many ADP simultaneously.
Multiple at a time!
What are all the Bioenergetics?
Energy, Free energy
Chemical energy < - > Potential energy
Kinetic energy < - > Heat (thermal energy)
Energy
can cause change and is not matter
Chemical energy
potential energy available for release in a chemical reaction
Goes with potential energy
Potential energy
energy that matter possesses because of its location or structure
Goes with Chemical energy
Kinetic energy
energy associated with motion
Goes with Heat (thermal energy)
Heat (thermal energy)
kinetic energy associated with random movement of atoms or molecules
Goes with Kinetic energy
Free energy
is the energy of a system available to do work
What are the Laws of Thermodynamics?
First law – Conservation of energy
Second law – Entropy
First law – Conservation of energy
Energy can be transferred and transformed, but it cannot be created or destroyed
Second law – Entropy
Every energy transfer or transformation generates some unusable energy This increases the entropy (disorder) of the universe
What are the two types of Free energy (G)?
exergonic reaction and endergonic reaction
exergonic reaction
proceeds with a net release of free energy (- ∆ G) and is spontaneous
endergonic reaction
absorbs free energy (+∆ G ) from its surroundings and is nonspontaneous
How is “energy” associated with ATP?
Phosphorylation couples an endergonic reaction with the breakdown of ATP (exergonic), the change in free energy can be driven to a negative value resulting in an exergonic reaction.