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Mechanisms labelled that "need to be known" are for Dr. Ge's class. May differ for each class.

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25 Terms

1

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Regioselective Reaction

<p>Regioselective Reaction</p>

2

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Stereoselective Rx

<p>Stereoselective Rx</p>

3

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Reduction of Alkene

Hydrogenation

<p>Reduction of Alkene</p><ul><li><p>Hydrogenation</p></li></ul><p></p>

4

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Reduction of Alkyne

Hydrogenation

<p>Reduction of Alkyne</p><ul><li><p>Hydrogenation</p></li></ul><p></p>

5

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Reduction of Alkyne

Hydrogenation syn addition of H₂
MUST KNOW MECHANISM

<p>Reduction of Alkyne</p><ul><li><p>Hydrogenation syn addition of H<sub>2</sub></p></li><li><p><mark data-color="red" style="background-color: red; color: inherit;">MUST KNOW MECHANISM</mark></p></li></ul><p></p>

6

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Reduction of Alkyne

Hydrogenation anti addition of H₂
MUST KNOW MECHANISM

<p>Reduction of Alkyne</p><ul><li><p>Hydrogenation anti addition of H<sub>2</sub></p></li><li><p><mark data-color="red" style="background-color: red; color: inherit;">MUST KNOW MECHANISM</mark></p></li></ul><p></p>

7

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Reduction of Alkyl halide

SN2

<p>Reduction of Alkyl halide</p><ul><li><p>SN2</p></li></ul><p></p>

8

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Reuction of Epoxide

SN2

<p>Reuction of Epoxide</p><ul><li><p>SN2</p></li></ul><p></p>

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Epoxidation

<p>Epoxidation</p>

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<p></p>

Epoxidation

<p>Epoxidation</p>

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Epoxidation

<p>Epoxidation</p>

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Syn Dihydroxylation

MUST KNOW MECHANISM

<p>Syn Dihydroxylation</p><ul><li><p><mark data-color="red" style="background-color: red; color: inherit;">MUST KNOW MECHANISM</mark></p></li></ul><p></p>

13

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Syn Dihydroxylation

MUST KNOW MECHANISM

<p>Syn Dihydroxylation</p><ul><li><p><mark data-color="red" style="background-color: red; color: inherit;">MUST KNOW MECHANISM</mark></p></li></ul><p></p>

14

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Syn Dihydroxylation

MUST KNOW MECHANISM

<p>Syn Dihydroxylation</p><ul><li><p><mark data-color="red" style="background-color: red; color: inherit;">MUST KNOW MECHANISM</mark></p></li></ul><p></p>

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<p>WITH LiAlH4; H2O!</p>

WITH LiAlH4; H2O!

Anti Dihydroxylation

Just mCPBA alone makes epoxide

<p>Anti Dihydroxylation</p><ul><li><p>Just mCPBA alone makes epoxide</p></li></ul><p></p>

16

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Anti Dihydroxylation

<p>Anti Dihydroxylation</p>

17

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Oxidative cleavage

<p>Oxidative cleavage</p>

18

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Ozonolysis

Internal alkyne

<p>Ozonolysis </p><ul><li><p>Internal alkyne</p></li></ul><p></p>

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Ozonolysis

Terminal alkyne

<p>Ozonolysis</p><ul><li><p>Terminal alkyne</p></li></ul><p></p>

20

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Oxidation of primary alcohol

PCC

<p>Oxidation of primary alcohol</p><ul><li><p>PCC</p></li></ul><p></p>

21

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Oxidation of primary alcohol

Jones

<p>Oxidation of primary alcohol</p><ul><li><p>Jones</p></li></ul><p></p>

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Oxidation of secondary alcohol

Makes a ketone

<p>Oxidation of secondary alcohol</p><ul><li><p>Makes a ketone</p></li></ul><p></p>

23

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Oxidation of secondary alcohol

<p>Oxidation of secondary alcohol</p>

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Epoxidation of allylic alcohols

(+)-DET = O added BELOW

<p>Epoxidation of allylic alcohols</p><ul><li><p>(+)-DET = O added <strong>BELOW</strong></p></li></ul><p></p>

25

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Epoxidation of allylic alcohols

(-)-DET = O added ABOVE

<p>Epoxidation of allylic alcohols</p><ul><li><p>(-)-DET = O added <strong>ABOVE</strong></p></li></ul><p></p>

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