Ketone and Aldehyde Reagents

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Reagents involved in CH 19 Reactions

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12 Terms

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<p>Oxidation of Primary Alcohols (<span style="color: red"><strong>Aldehyde</strong></span>)</p>

Oxidation of Primary Alcohols (Aldehyde)

(1) PCC, CH2CL2

(2) DMP, CH2CL2

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<p>Ozonolysis of Alkenes (<span style="color: red"><strong>Aldehyde</strong></span>)</p>

Ozonolysis of Alkenes (Aldehyde)

(1) 03, (2) DMS

<p>(1) 0<sub>3, </sub>(2) DMS</p>
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<p>Hydroboration-Oxidation of Terminal Alkynes (<span style="color: red"><strong>Aldehyde</strong></span>)</p>

Hydroboration-Oxidation of Terminal Alkynes (Aldehyde)

(1) R2B-H, (2) H2O2, NaOH

<p>(1) R<sub>2</sub>B-H, (2) H<sub>2</sub>O<sub>2, </sub>NaOH</p>
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<p>Oxidation of Secondary Alcohols (<span style="color: purple"><strong>Ketone)</strong></span></p>

Oxidation of Secondary Alcohols (Ketone)

Na2Cr2O7, H2SO4, H20

<p><span>Na</span><sub>2</sub><span>Cr</span><sub>2</sub><span>O</span><sub>7</sub><span>, H</span><sub>2</sub><span>SO</span><sub>4</sub><span>, H</span><sub>2</sub><span>0</span></p>
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<p>Ozonolysis of Alkenes (<span style="color: purple"><strong>Ketone)</strong></span></p>

Ozonolysis of Alkenes (Ketone)

(1) O3, (2) DMS

<p>(1) O<sub>3,</sub> (2) DMS</p>
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<p>Acid-Catalyzed Hydration of Terminal Alkynes (<span style="color: purple"><strong>Ketone)</strong></span></p>

Acid-Catalyzed Hydration of Terminal Alkynes (Ketone)

H2SO4, H2O, HgSO4

<p>H<sub>2</sub>SO<sub>4, </sub>H<sub>2</sub>O, HgSO<sub>4</sub></p>
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<p>Friedel-Crafts Acylation (<span style="color: purple"><strong>Ketone</strong></span>)</p>

Friedel-Crafts Acylation (Ketone)

AlCl3 and Acyl Halide (Ketone w Halide Group)

<p>AlCl<sub>3 and </sub>Acyl Halide (Ketone w Halide Group)</p>
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<p>Acetal</p>

Acetal

2 ROH

<p>2 ROH</p>
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PCC

Oxidizing agent

Primary alcohol — will oxidize to aldehyde

Secondary alcohol — will oxidzied to ketone

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DMP

Oxidizing agent

Primary alcohol — will oxidize to aldehyde

Secondary alcohol — will oxidzied to ketone

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Na2Cr2O7, H2SO4, H2O

Oxidizing agent(s)

Primary alcohol — will oxidize to carboxylic acid

Secondary alcohol — will oxidize to ketone

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<p>Friedel-Crafts Acylation</p>

Friedel-Crafts Acylation

Installation of Aldehyde/Ketone Group (AlCl3 + Acyl Halide)

<p>Installation of Aldehyde/Ketone Group (AlCl<sub>3</sub> + Acyl Halide)</p>

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