Ketone and Aldehyde Reagents
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Description and Tags
Reagents involved in CH 19 Reactions
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12 Terms
Oxidation of Primary Alcohols (Aldehyde)
(1) PCC, CH2CL2
(2) DMP, CH2CL2
Ozonolysis of Alkenes (Aldehyde)
(1) 03, (2) DMS
Hydroboration-Oxidation of Terminal Alkynes (Aldehyde)
(1) R2B-H, (2) H2O2, NaOH
Oxidation of Secondary Alcohols (Ketone)
Na2Cr2O7, H2SO4, H20
Ozonolysis of Alkenes (Ketone)
(1) O3, (2) DMS
Acid-Catalyzed Hydration of Terminal Alkynes (Ketone)
H2SO4, H2O, HgSO4
Friedel-Crafts Acylation (Ketone)
AlCl3 and Acyl Halide (Ketone w Halide Group)
Acetal
2 ROH
PCC
Oxidizing agent
Primary alcohol — will oxidize to aldehyde
Secondary alcohol — will oxidzied to ketone
DMP
Oxidizing agent
Primary alcohol — will oxidize to aldehyde
Secondary alcohol — will oxidzied to ketone
Na2Cr2O7, H2SO4, H2O
Oxidizing agent(s)
Primary alcohol — will oxidize to carboxylic acid
Secondary alcohol — will oxidize to ketone
Friedel-Crafts Acylation
Installation of Aldehyde/Ketone Group (AlCl3 + Acyl Halide)
Note 
Flashcards (24)