Chem 120b presentation

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4 Terms

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Descriptive interpretation

Larger bubbles were created in cathode, which corresponds with the Cathode half-reaction in the water-splitting theory. ​

Bubbles are produced faster from the anode, because there are more oxygen anions present than cations, due to compound composition, speeding up oxidation.

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Interpretation of Qualitative Data

  • Compound X and V (La₂NiO₄) ​

  • Only has one transition metal: Nickel

  • Had high bubble production

  • Having only Nickel maintains stability in octahedra structure of perovskite which allows for better catalytic performance. ​

  • Compound Y and W (La₂Ni1-xCoxO4)​

  • Contains extra transition metal: Cobalt

  • Had lower bubble production​Cobalt, can cause structural distortion, lowering catalytic performance. ​

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Discussion Limitations

  • Lack of precise instruments ​

  • Amount of trials is restricted to 2​

  • Hygroscopic materials

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Discussion of Future Plans

  • Use precise measuring instruments to quantitatively determine the catalytic performance of different Ruddlesden poppers ​

  • Use an electron microscope to visualize morphology of Ruddlesden poppers to test Cobalt structure distortion theory ​

  • Retest compounds during electrolysis in various conditions (e.g. higher or lower temperatures) and observe changes in performance​