Oxidation FGIs
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6 Terms
1
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RC(-OH)R → RC(=O)R (secondary alcohol to ketone)
CrO3, H+ reflux
2
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RC(-OH)R → RC(=O)R (primary alcohol to ketone)
CrO3, H+ distillation (or milder oxidant e.g. PCC)
3
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RHC-OH → RCO2H (primary alcohol to carboxylic acid)
CrO3, H+ reflux
4
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Ph-CH3 → Ph-COOH
KMnO4 (potassium permanganate)
5
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RH2C=CH3 → peroxide
RCO3H (peracid)
6
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RH2C=CH3 → RH(HO-)C-C(-OH)H2 (alkene to diol)
aq. OsO4
Note 
Flashcards (66)