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unsaturated solution
solution that contains less solute than it has the capacity to dissolve
saturated solution
solution that contains the maximum amount of solute that will dissolve in a solvent at a specific temp
supersaturated solution
solution that contains more dissolved solute than it present in a saturated solution
solution formation
solute dissolves in a solvent to form a solution
to form a liquid solution, the solute needs to separate into individual components, overcome IMF to make room and expand, than allow the solute and solvent to form a solution
predicting solubility for solids
increases with increasing temperature
predicting solubility for gases
decreases with increasing temperature
intermolecular forces
London Dispersal < Dipole-Dipole < Hydrogen Bonding < Ion-Dipole
entropy factors
increasing temperature, volume, number of molecules, and complexity of molecules all increases the entropy of the substance due to microstates
When ∆H is (-) and ∆S is (+)
∆G is (-) so always spontaneous
When ∆H is (+) and ∆S is (-)
∆G is (+) so never spontaneous
When ∆H is (-) and ∆S is (-)
∆G is (-) at low temperatures but (+) at high temperatures
When ∆H is (+) and ∆S is (+)
∆G is (+) at low temperatures but (-) at high temperatures