Alpha Carbon Chemistry

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11 Terms

1
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First

__________ step of citric acid cycle uses aldol reaction

2
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Fructose-1,6-bisphosphate

Cleavage of ____________________________ in glycolysis and formation of it in gluconeogenesis are aldol and retro-aldol reactions

3
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Weaker

Equilibrium favors formation of the __________ acid

4
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Reactant
Product

pKa(___________ acid) - pKa(__________ acid) = pKeq

5
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LDA

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6
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Kinetic

________________ enolate forms faster

7
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Thermodynamic

______________ enolate is more stable

8
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Small
High

_______________ base and __________ temperature favors thermodynamic enolate

9
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Large
Low

_______________ base and __________ temperature favors kinetic enolate

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Aldol

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11
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Retro aldol

_________________ reaction is exact reverse of aldol reaction