Carboxylic Acids
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6 Terms
1
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Old reactions to form Carboxylic Acid
1-Substituted alcohol + Na2CrO7/H2SO4
Aldehyde + KMnO4/H2O
Benzylic carbon + KMnO4/H2O
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New reactions (carbon elongation)
CN + RX = R-CN
R-CN + H3O+ = R-C-COOH
Grignard + CO2/H3O+
Alkyllithium + CO2
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Carboxylic Acids undergo what type of reactions?
Addition-elimination
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2 mechanisms of addition-elimination
Acid catalyzed, base catalyzed
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4 Addition-elimination reactions of carboxylic acids
SoCl2 - Cl
RC=OCl - RC=O
ROH - OR
RNH2 - NHR
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1 Redox reaction
LAH/H3O+ - ROH
Note 
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