define internal energy
the sum of the kinetic energy due to random motion of particles and potential energy due to forces of attraction between the particles
internal potential vs internal
internal is change in temp. potential is change in state ONLYY
define heat capacity
heat capacity, C, is the amount of heat required to raise the temp of a substance by 1K pr 1C
heat capacity formula
Q = C(change in temp.) depends on mass and material
define specific heat capacity
The amount of heat needed to raise the temperature of 1g (or unit mass) of substance by 1K or 1C
formula of specific heat capacity
change in thermal energy = mass x SHC x temperature change
Q = mc(change in temp.)
what is melting and solidification?
melting is chg frm solid to liquid when energy is transferred to the substance (pure substance melting constant temp!) solidification is just the opp and its js melting (energy transferred out)
boiling and condensation
changes between liquid and gas when energy is transferred to the substance. the reverse is just condensation, energy is transferred out
What is latent heat? (hidden heat)
Latent hear is the energy absored or released to change the state of a substance at constant temp
latent heat in terms of behaviour of particles
energy supplied is used to do work against the forces of attraction bewteen the particles/ energy released to the surroundings causes the forces of attraction to reform around the particles
The particles now have a wider/smaller range of movement and the average distance of the particles increases/decreases. this increases the internal potential energy of the substance whereas the internal kinetic energy remains constant
define latent heat of fusion
The quantity of heat energy required/released to convert a substance of solid to liquid without any temperature change.
define specific latent heat of fusion
The quantity of heat energy required/released to convert a unit mass of substance of solid to liquid without any temperature change.
formula for specific latent heat of fusion/vapourisation
Lf = mlf/Lv = mlv OR Q = m*lf/lv
define evaporation
The change of a substance from a liquid to a gas without boiling
how does evaporation occur
The particles in a liquid are always moving randomly at different speeds.
Particles at the surface of the liquid can escape into the atmosphere if they have sufficient kinetic energy to overcome attractive forces of other liquid particles and do work against atmosphere
less energetic particles are left behind and so the temp decrease
factors affecting rate of evaporation
temperature, surface area, humidity, windspeed, pressure, nature of the liquid