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From lecture 1 of Solid states and Diffraction
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What dictates the macroscopic properties of a material
The microscopic structure
What are the 4 main types of solid structures
-Molecular solids
-Covalent networks
-Metallic solids
-Ionic solids
Describe Molecular Solids
-Molecular solids, such as iodine where there are strong covalent bonds within molecules but weak intermolecular attractions between
Describe Covalent Networks
-Covalent networks, such as silicone where each atom forms four covalent bonds with each other forming a lattice structure.
Describe Metallic solids
-Metallic solids, such as iron these join metal cations with a sea of delocalised electrons too form a solid
Describe Ionic Solids
-Ionic solids, such as sodium chloride where ions are held in a lattice by electrostatic attraction.
Describe allotropes and use an example
-Allotropes, are different structural forms of the same element. For example carbon forms allotropes of diamond, graphite, and buckminsterfullerene.
-Diamond is hard, insulating, abrasive. In giant covalent network forming lattice structure.
-Graphite is soft, conducting, and lubricating. Forms covalent network of layers of carbon.
Describe what a polymorph is, use a brief example
-Polymorphs, are different crystal structures of the same compound. For example SiO4 forms both quartz and B-cristobalite.