Chemistry - 8 Rates and Equilibrium - 8.4 The Effect of Concentration and Pressure & 8.5 The Effect of Catalysts & 8.6 Reversible Reactions

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21 Terms

1

The effect of concentration on rate of reaction [3]:

- as concentration increases, there are more particles in the same volume
- particles collide more frequently
- the rate of reaction increases

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2

The effect of (gas) pressure on rate of reaction [3]:

- as pressure increases, there are more particles in a given space
- particles collide more frequently
- the rate of reaction increases

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3

Marble chemical formula

CaCO₃ (calcium carbonate)

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4

CaCO₃ + HCl →

CaCl₂ + CO₂ + H₂O

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5

Catalyst

substance that speeds up the rate of a chemical reaction but is unchanged itself

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6

The effect of catalysts on rate of reaction [3]:

- catalyst provides an alternative reaction pathway requiring less activation energy
- more particles have the required activation energy
- there are more successful collisions
- the rate of reaction increases

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7

Advantages of catalysts [4]:

- less energy required
- lower temperatures and pressures
- conserves fossil fuels
- less expensive

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8

A catalyst cannot be used indefinitely because...

it becomes 'poisoned' by reaction with impurities

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9

Reversible reaction

a chemical reaction in which the products reform the original reactants

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10

Reversible reaction symbol

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11

Difference between reactions in a reversible reaction

one is endothermic while the other is exothermic

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12

How to change the direction of a reversible reaction

change conditions so equilibrium shifts

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13

Litmus alternative name

HLit

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14

Litmus reversible reaction

HLit ⇌ H⁺ + Lit⁻

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15

Litmus in acids

HLit (red)

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16

Litmus in alkalis

H⁺ + Lit⁻ (blue)

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17

Examples of reversible reactions [3];

- litmus paper
- salts and water of crystallisation
- ammonium chloride

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18

Salts and water of crystallisation reversible reaction:

hydrated salt ⇌ anhydrous salt + water

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19

Ammonium chloride reversible reaction:

NH₄Cl ⇌ NH₃ + HCl

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20

Ammonium chloride forward reaction [2]

- thermal decomposition
- products become gases

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21

Ammonium chloride backward reaction [2]

- gases cool and react
- form solid

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