CHEM122 Acid & Bases

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35 Terms

1
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What do acids produce in aqueous solutions?

Hydrogen ions (H+).

2
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What is the Brønsted-Lowry definition of an acid and a base?

An acid is a proton donor, and a base is a proton acceptor.

3
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What is the equilibrium constant for the dissociation of an acid?

K_a = [H3O+][A-]/[HA].

4
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What characterizes a strong acid in terms of equilibrium?

The equilibrium lies far to the right, indicating a large K_a value.

5
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What is the relationship between weak acids and their conjugate bases?

Weak acids yield strong conjugate bases.

6
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How is the dissociation constant of water (K_w) defined at 25°C?

K_w = [H3O+][OH-] = 1.0 × 10^-14.

7
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How to calculate pH for a strong acid like HCl?

Use the formula pH = -log[H3O+], where [H3O+] equals the concentration of the acid.

8
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For a weak acid, what is the expression for K_a?

K_a = [H3O+][A-]/[HA], where A- is the conjugate base.

9
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What does it mean for a substance to be amphoteric?

It can act as both an acid and a base.

10
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In what pH range does water naturally exist?

pH of 7, indicating neutrality.

11
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What factors influence the pH of salt solutions?

The nature of the cations and anions present in the solution.

12
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What are polyprotic acids?

Acids that can donate more than one proton, leading to multiple dissociation steps.

13
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How is the strength of acids qualitatively analyzed?

Based on molecular structure and electronegativity.

14
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What is the Henderson-Hasselbalch equation used for?

Calculating the pH of buffered solutions.

15
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What defines a Lewis acid?

An electron pair acceptor.

16
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What is a characteristic of the first dissociation of polyprotic acids?

It is typically the strongest dissociation.

17
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How to determine the pH of a buffer solution?

Use the Henderson-Hasselbalch equation: pH = pKa + log([A-]/[HA]).

18
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What is the effect of strong acids on buffer solutions?

They cause a slight decrease in pH but the buffer resists drastic changes.

19
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What does the dissociation constant (Ksp) indicate?

The equilibrium between a saturated solution of a salt and its ions.

20
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How can the pH of a solution of calcium hydroxide be calculated?

From its Ksp value by determining the concentration of hydroxide ions.

21
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What is a common property of acids?

They taste sour.

22
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What is a common property of bases?

They taste bitter and feel slippery.

23
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What is the pH scale range for acids?

Below 7.

24
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What is the pH scale range for bases?

Above 7.

25
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What is an example of a strong acid?

Hydrochloric acid (HCl).

26
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What is an example of a strong base?

Sodium hydroxide (NaOH).

27
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What is the importance of the pH scale?

It measures the acidity or basicity of a solution.

28
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What is the effect of increasing the concentration of H3O+ on pH?

pH decreases.

29
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What is the effect of increasing the concentration of OH- on pH?

pH increases.

30
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What is the dissociation of water?

Water dissociates into H3O+ and OH-.

31
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What is a neutralization reaction?

It is a reaction between an acid and a base producing water and salt.

32
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What is a buffer solution?

A solution that resists changes in pH upon the addition of small amounts of acid or base.

33
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What are Lewis bases?

Substances that can donate an electron pair.

34
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What is the conjugate acid of NH3?

NH4+.

35
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What is the conjugate base of H2SO4?

HSO4-.