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Atomic#
Mass #
Mass # = total # of protons(p+) + neutrons(n0)
# of neutrons
(n0) = Mass # - Atomic #
Dalton’s atomic theory
1. All elements are composed of tiny indivisible particles called atoms
2. Atoms of the same elements are identical-false!
3. Atoms of different elements can physically mix together or combine in simple whole # ratios to form compounds
4. Chemical reactions occur when atoms separate, join or rearrange
J. J. Thomson
Discovered electrons - cathode ray
Robert Millikan
Mass of electron - Oil drop experiment (mass = 5.4 x 10-4 of H)
Ernest Rutherford
Nucleus and Protons- Gold Foil Experiment
James Chadwick
Neutron
Alpha Particle
Lowest Penetration (0.05 mm)
Symbol=He or α
Mass = 4
charge = +2
Paper/clothes
Beta Particle
Moderate
4 mm body tissue
symbol = β
Mass = 0
charge = -1
Shielding – metal foil
Gamma particle
very high
symbol = γ
mass and charge is 0
Shielding – lead, concrete
Half-Life Calculation
(t1/2)
Time required for half of the original amount to decay
Nuclear Equation
Conservation of Mass
– Mass number of reactants MUST equal the
mass number of product (top)
– Atomic number of reactant MUST equal the
atomic number of product (bottom)
Dalton model of atom
solid invisible mass
J.J. Thomson model of atom
“Plum-pudding” model
Ernest Rutherford model of atom
e- surrounding a dense nucleus
Niels Bohr model of atom
e- traveling in circular paths called “orbits”(energy levels)
Erwin Schrödinger model of atom
“Quantum Mechanical” model
Quantum numbers
Describes the location of any electrons
Principal of quantum numbers
energy level (distance from the nucleus) (n = 1, 2, 3, ...)
Orbital of quantum numbers
shape of orbitals (s, p, d, f) (region of space of finding e-)
Electron Configuration
Arrangement of electron
Aufbau principle
e- enters the lowest energy level 1st
• 1s, 2s, 2p, 3s, 3p, 4s, 3d, 4p, 5s, 4d, 5p, 6s, 4f, 5d, 6p, 7s, 5f, 6d, 7p
Pauli exclusion principle
an atomic orbital may describe at most 2e- (NO 2e- may have the same Q#) (e- may either spin up or down)
Hund’s rule
when e- occupy orbitals of equal
energy, 1e- enter each orbital until all the orbitals
contain 1e- w/parallel spin
Order of filling the orbitals
1s, 2s, 2p, 3s, 3p, 4s, 3d, 4p, 5s, 4d, 5p, 6s, 4f, 5d, 6p, 7s, 5f, 6d, 7p
Short-hand electron notation
Use group 18 (8A) (Noble gases) as the starting point. Noble gas MUST be 1 row above the element.
orbital notation
Use arrows for electron, and use lines to show the different kind.
Wavelength
distance from one peak to another peak
frequency
# of peaks per second (Hertz)
Lithium Flame Test
Red
Sodium Flame Test
yellow/orange
Potassium Flame Test
Lavender
Calcium Flame Test
Orange/red
Copper Flame Test
Green
Periodic Table 1st one
Mendeleev– Published the 1st table with elements arranged in similarities of their properties
• Increasing atomic weight
Revised periodic table
Henry Moseley-Rearrange the table in increasing A#
Periodic horizontal rows
7
Group – vertical columns
18
Representative groups
group a
Transition metals
group b G3 to G12
Inner transition metals
bottom 2 rows
Alkali metal
(G1 or G1A, except H) *very reactive
Alkaline earth metal
(G2 or G2A) *reactive
Halogen non-metal
(G17 or G7A)
Noble gas-where it is
(G18 or G8A) *Non-metal, gas, non- reactive
Ductile, malleable, shiny, solid, strong,
conducts heat and electricity
Metals
Most of the periodic table
– On the left side of the metalloids
Solid to gas, brittle, Does not conduct heat or
electricity
Non-metal
Metalloid
Semi-conductors, solid, separates metal from non-
metals – B, Si, Ge, As, Sb, Te and
At
Noble gas
completely filled s & p orbital (Except He – only filled s)
Representative
partially filled s or p orbital (Groups 1,2 and 13-18)
Transition
filled s and partially filled d orbitals (Groups 3-12)
Inner transition
filled s, d1 and partially filled f orbitals
Atomic radius Trend
½ the distance between nuclei of 2 like
atoms
• Group = bigger as ↓(go down) the group
• Period = smaller as →(go to the right) the period
Ionization energy def
Energy required to remove 1 e- from a neutral atoms
IE trend
Group = smaller as ↓ the group (bigger size, less attraction,
easier to remove e-, less IE)
• Period = bigger as → the period (smaller size, more
attraction, harder to remove e-, more IE)
Electronegativity Trend
Tendency of an atom to attract an e-
• Same trend as I. E
Amplitude
the maximum distance the particles of the medium move from their resting positions when a wave passes through.
Ground state
the lowest energy state of an atom or other particle.
Photon
a tiny particle that comprises waves of electromagnetic radiation.
Spectrum
Wavelength of light that is separated into color when passed through a prism
Quantum Def
energy required to move from a lower energy level to a higher one
Atomic Mass def
weighted average mass of the atom in a naturally occurring sample
Nuclear Force
energy that holds neutrons and protons together in the nucleus
Radiation
penetrating rays & particles emitted during radioactivity