Chapter 5: Nuclear Chemistry

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What does natural radioactivity comes from?

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Chemistry

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1

What does natural radioactivity comes from?

Unstable nuclei

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2

What are unstable nuclei found in?

Carbon, hydrogen, and elements with atomic numbers 20 or higher

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3

Unstable Nuclei

Nuclei in which the nuclear forces cannot offset the repulsions between the protons

  • Radioactive

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Radiation

Small particles of energy emitted by unstable nuclei to become more stable

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5

What are the forms of radiation?

  • alpha (α) particle

  • beta (β⁻) particle

  • positrons (β⁺)

  • gamma (γ) rays

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6

Radioisotope

An isotope of an element that emits radiation

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Are radioisotopes one isotope of an element?

No, they can be one or more

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How are radioisotopes named?

With the mass number

  • For example, iodine-131

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9

Alpha (α) particles

  • Definition, symbol, charge, mass number

Identical to helium nucleus

  • ⁴₂He

  • Mass Number = 4

  • Charge = 2+

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10

Beta (β⁻) particles

  • Definition, symbol, charge, mass number

High energy electrons

  • ⁰₋₁e

  • Mass Number = 0

  • Charge = 1-

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Positrons (β⁺)

  • Definition, symbol, charge, mass number

A positron is a particle with the same mass as an electron but with a positive charge

  • ⁰₊₁e

  • Mass Number = 0

  • Charge = 1+

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Gamma (γ) rays

  • Definition, symbol, charge, mass number

Pure energy

  • ⁰₀γ

  • Mass Number = 0

  • Charge = 0

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Proton (p)

  • Symbol, charge, mass number

Positively charged subatomic particle

  • ¹₁H

  • Mass Number = 1

  • Charge = 1+

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14

Neutron (n)

  • Symbol, charge, mass number

Neutrally charged subatomic particle

  • ¹₀n

  • Mass Number = 1

  • Charge = 0

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15

Biological Effects of Radiation

Ionizing radiation strikes molecules in its path and…

  • knocks away the electrons in molecules, forming unstable ions such as H₂O⁺

  • causes undesirable chemical reactions

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16

What happens to the cells when a biological species is hit with radiation?

It damages cells most sensitive to radiation, rapidly dividing cell in bone marrow, skin and reproductive organs, thus causing cancer

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Alpha (α) particle

  • Travel distance in air, tissue depth(penetration), shielding, typical source

Travel distance in air: 2-4 cm

Tissue depth(penetration): 0.05 mm

Shielding: Paper, clothing

Typical Source: Radium-226

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Beta (β⁻) particle

  • Travel distance in air, tissue depth(penetration), shielding, typical source

Travel distance in air: 200-300 cm

Tissue depth(penetration): 4-5 mm

Shielding: Heavy clothing, lab coats, gloves

Typical Source: Carbon-14

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Gamma (γ) rays

  • Travel distance in air, tissue depth(penetration), shielding, typical source

Travel distance in air: 500mm

Tissue depth(penetration): 50 cm or more

Shielding: Lead, thick concrete

Typical Source: Technetium-99m

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20

For those working in an environment where radioactive materials are present, how do you limit exposure?

  • Minimizing the time spent near a radioactive source

  • Increase distance from the source

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21

Radioactive Decay

A process in which the nucleus breaks down

  • represented by a nuclear equation

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Nuclear Equation (what it’s like)

The mass number and atomic number may change

  • The sum of the mass numbers are equal and the atomic numbers are equal for products and reactants

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Alpha Decay

  • Relate to nuclear equation

Occurs when a radioactive nucleus emits an alpha particle, forming a new nucleus with a mass number that is decreased by 4 and an atomic number that is decreased by 2

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Beta Decay

  • Relate to nuclear equation

In the nuclear equation, the mass number of the new nucleus remains the same, and its atomic number increases by 1

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Positron Emission

  • Relate to nuclear equation

A proton is converted to a neutron and a positron

¹₁p → ¹₀n + ⁰₋₁e

  • The mass number of the new nucleus is the same, but the atomic number decreases by 1

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Gamma Radiation

  • Relate to nuclear equation

Energy emitted from an unstable nucleus, indicated by m following the mass number

  • The mass number and the atomic number of the nucleus are the same

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27

What should be in place of the ?

  • ⁴⁹₂₅Mn → ? + ⁰₊₁e

    • What type of nuclear reaction is this?

⁴⁹₂₄Cr

  • Positron Emission

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28

What should be in place of the ?

  • ⁴²₁₉K → ? + ⁰₋₁e

    • What type of nuclear reaction is this?

⁴²₂₀Ca

  • Beta Decay

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29

What should be in place of the ?

  • ²⁵¹Cf₉₈ → ? + ⁴₂He

    • What type of nuclear reaction is this?

²⁴⁷₉₆Cm

  • Alpha Decay

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30

What should be in place of the ?

  • ? → ⁹⁹₄₃Tc + ⁰₀γ

  • What type of nuclear reaction is this?

⁹⁹^m₄₃Tc (basically in the exponent position its 99m)

  • Gamma Radiation

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31

How are radioactive isotopes produced?

  • What is the process called?

When a stable nucleus is converted to a radioactive nucleus by bombarding it with a small particle

  • Transmutation (nuclear)

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32

Label the parts in this transmutation process:

  • ⁴₂He + ¹⁰₅B → ¹³₇N + ¹₀n

⁴₂He = bombarding particle

¹⁰₅B = stable nucleus

¹³₇N = new radioactive nucleus

¹₀n = neutron

  • It can be any particle though

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33

Geiger Counter

  • How does it work?

A common instrument that detects alpha particle, beta particles, and gamma rays

  • It uses ions produced by radiation to create an electrical current

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34

Units for measuring radiation (list)

  • Which is a common unit and which are SI units?

  • What are the pairs?

  • Curie = common unit

  • Becquerel = SI unit

  • Rad = common unit

  • Gray = SI unit

  • Rem = common unit

  • Sievert = SI unit

Common + SI Unit Pairs:

  • Curie and Becquerel

  • Rad and Gray

  • Rem and Sievert

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35

Curie

  • Definition, abbreviation, equivalent

The number of disintegrations that occurs in 1g of radium

  • Ci

  • 3.7 x 10¹⁰ disintegrations per second

    • 3.7 x 10¹⁰ disintegrations/s = 1 Ci

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Becquerel

  • Definition, abbreviation, equivalent

The SI unit of radiation activity

  • Bq

  • 1 disintegration per second

    • 1 disintegration/s = 1 Bq

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Relation between Ci and Bq

1 Ci = 3.7 x 10¹⁰ Bq

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Rad

  • Definition, abbreviation

Radiation absorbed dose--measures the amount of radiation absorbed by a gram of material such as body tissue

  • rad is the abbreviation

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Gray

  • Abbreviation, equivalent

Gy

  • 1 Gy = 1 (J/Kg) of tissue

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40

Relation between rad and gy

1 Gy = 100 rad

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Rem

  • Definition, abbreviation

The radiation equivalent in humans--measures biological effects(damage) of different kinds of radiation

  • Rem is the abbreviation

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42

Sievert

  • Abbreviation

Sv

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43

Relation between Rem and Sv

1 Sv = 100 rem

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44

Match each(radiation) with it’s unit of measurement:

  • Activity

  • Absorbed Dose

  • Biological Damage

Activity = Ci or Bq

Absorbed Dose = Rad or Gy

Biological Damage = Rem or Sv

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45

Dosimeters

Detect them amount of radiation exposure from

  • X-rays

  • Gamma rays

  • Beta particles

Usually worn as a tag-like device on clothing

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46

What are some every day things that expose us to low levels of radiation?

  • Buildings where we live and work

  • Food and water

  • The air we breathe

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47

What is an LD₅₀?

Lethal dose

  • The amount of something it takes to kill half of an observed population

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48

LD₅₀ of radiation in Sv for

  • Insects

  • Bacterium

  • Rats

  • Humans

  • Dogs

Insects = 1000 Sv

Bacterium = 500 Sv

Rats = 8 Sv

Humans = 5 Sv

Dogs = 3 Sv

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49

Half-life

The time it takes for the radiation of a radioisotope to decrease(decay) to half the original value

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50

What radioisotope is used to date really old biological things due to its long half-life?

Carbon-14

  • It has a half-life of 5730 years

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51

Decay Curves

Illustrate the amount of time that is required for half of the substance to be converted into a different element

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52

If the radioisotope of strontium-90 has a half-life of 35.1 years, how many mg of a 36.0mg sample will remain after 152.4 years?

152.4 yr(1 half-life/35.1 yr) = 4 half-lives

36 → 18 → 9 → 4.5 → 2.25 2.25mg remains

  • Each arrow is a half-life

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53

What types of radioisotopes are used in medical applications?

  • Why?

Radioisotopes with short half-lives because…

  • the cells in the body do not differentiate between nonradioactive atoms and radioactive atoms

  • they decay within a few months of use

    • To avoid any bad damage to healthy cells

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54

How is a radioisotope used in medical applications?

Once the radioisotope is incorporated into cells, the radioactive atoms can be detected as they emit radiation, giving an image of an organ

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Scans with radioisotopes

  • After the radioisotope is ingested by the patient

  • The scanner moves slowly over the organ where the radioisotope is absorbed

  • The radiologist determines the level and location of the radioactivity emitted by the radioisotope

  • The gamma rays emitted from the radioisotope can be used to expose a photographic plate, producing a scan of the organ

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Positron Emission Tomography (PET)

Positron emitters with short half-lives

  • can be used to study brain function, metabolism, and blood flow

  • combine with electrons after emission to produce gamma rays, which are then detected by computers, creating 3D image of the organ

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What are some examples of positron emitters with short half-lives

carbon-11, oxygen-15, nitrogen-13, flourine-18

¹⁸₉F → ¹⁸₈O + ⁰₊₁e

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Computed Tomography (CT)

An imaging method used to scan organs such as the brain, lungs, and heart

  • A computer monitors the absorption of 30000 x-ray beams directed at the brain in successive layers

  • Differences in absorption based on tissue densities and fluids provide images of the brain

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Magnetic Resonance Imaging (MRI)

An imaging technique that doesn’t require nuclear radiation

  • Is the least invasive imagine method available

  • Based on the absorption of energy when protons in hydrogen atoms are excited by a strong magnetic field

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60

Why does an MRI work?

It works because the energy absorbed is converted to color images of the body

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61

Nuclear Fission Reaction

A large nucleus is bombarded with a neutron, making an unstable isotope

  • The large nucleus then splits into two smaller nuclei and three neutrons

¹₀n + ²³⁶₉₂U → ²³⁷₉₂U → ⁹¹₃₆Kr + ¹⁴³₅₆Ba + 3¹₀n

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Atomic energy

Large amount of energy generated by the splitting of a large nuclei in a nuclear fission reaction

OR

The leftover mass that comes from the fusing of nuclei in a nuclear fusion reaction

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63

How is nuclear fission used in power plants?

It is used to keep the systems cool so the reaction doesn’t get out of hand

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64

What is a nuclear chain reaction?

In nuclear fission, the resulting neutrons of one reaction bombard and cause fission in other nuclei

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Nuclear Fusion Reaction

Atomic nuclei of low atomic number fuse to form a heavier nucleus with the release of energy

Ex. Hydrogen isotopes combine in a fusion reaction to produce helium, a neutron, and energy

  • ³₁H + ²₁H → ⁴₂He + ¹₀n + energy

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66

What temperatures are necessary for fusion reactions?

Very high

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67

Radioactive Decay vs Nuclear Fission

Nuclear fission: The splitting of one large atomic nucleus into smaller fragments

Radioactive decay: The change of a less stable nucleus to a more stable nucleus

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