Unit 6 Molec. Geom. Hybridization, Angles, and polarity

Hybridization of central atom on a Linear Electronic Structure

sp

Hybridization of central atom on a Trigonal Planar Electronic Structure

sp²

Hybridization of central atom on a Tetrahedral Electronic Structure

sp³

Hybridization of central atom on a Trigonal Bipyramidal Electronic Structure

sp³d

Hybridization of central atom on a Octahedral Electronic Structure

sp³d²

Bond angle of a linear linear structure

180

Bond angle of a Trigonal planar trigonal planar structure

120

Bond angle of a trigonal planar bent structure

less than 120 (<120)

Bond angle of a tetrahedral tetrahedral structure

109.5

Bond angle of a tetrahedral trigonal pyramidal structure

less than 109.5 (<109.5)

Bond angle of a tetrahedral bent structure

less than less than 109.5 (<<109.5)

Bond angle of a Trigonal bipyramidal trigonal bipyramidal structure

90/120

Bond angle of a Trigonal bipyramidal see-saw structure

<90/<120

Bond angle of a Trigonal bipyramidal T-shaped structure

less than less than 90 (<90)

Bond angle of a Trigonal bipyramidal linear structure

180

Bond angle of a octahedral octahedral structure

90, 90

Bond angle of a octahedral square pyramidal structure

<90, 90

Bond angle of a octahedral square planar structure

90

Bond angle of a octahedral T-shaped structure

<90

Linear linear structure: polar?

no

Trigonal planar trigonal planar: polar?

no

Trigonal planar bent: polar?

yes

Tetrahedral tetrahedral: polar?

no

Tetrahedral trigonal pyramidal: polar?

yes

Tetrahedral bent: polar?

yes

Trigonal bipyramidal trigonal bipyramidal: polar?

no

Trigonal bipyramidal see-saw: polar?

yes

Trigonal bipyramidal T-shaped: polar?

yes

Trigonal bipyramidal linear: polar?

yes

Octahedral octahedral: polar?

no

Octahedral square pyramidal: polar?

yes

Octahedral square planar: polar?

yes

Octahedral T-shaped: polar?

yes