Chapter 14: Solids and Liquids

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30 Terms

1

Intermolecular Forces

Attractive forces that occur between molecules.

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2

Intramolecular Forces

Attractive forces that occur between atoms in a molecule; chemical bonds.

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3

Dipole-Dipole Attraction

Attractive force between the positively charged end of one molecule with the negatively charged end of another polar molecule.

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4

Hydrogen Bonding

Special name for unusually strong dipole-dipole attractions that occur among molecules in which hydrogen is bonded to a highly electronegative atom(such as nitrogen, oxygen, or fluorine).

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5

London Dispersion Forces

Relatively weak intermolecular forces resulting from a temporarily uneven distribution of electrons that induces a dipole in a neighbor. Instantaneous dipole forces for non polar molecules

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6

Normal Boiling Point

The boiling temperature of a liquid under one atmosphere of pressure. The temperature at which the vapor pressure of a liquid is exactly one atmosphere.

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7

Heating/Cooling Curve

knowt flashcard image
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8

Normal Freezing Point

The freezing temperature of a liquid under one atmosphere of pressure.

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9

Molar Heat of Fusion

The energy required to melt one mole of a solid.

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10

Molar Heat of Vaporization

The energy required to vaporize one mole of a liquid.

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11

Vaporization (evaporation)

The process in which a liquid is converted to a gas.

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12

Condensation

The process in which a vapor is converted to a liquid.

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13

Vapor Pressure

The pressure exerted by a vapor in equilibrium with its liquid phase at a certain temperature.

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14

Crystalline solids

A solid characterized by the regular arrangement of its components.

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15

Ionic Solids

A solid that contains cations and anions.

Does not conduct as a solid but does as a liquid

Kbr, AgNO3, Cs2O are examples of.

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16

Molecular Solids

A solid composed of molecules.

type of solid with very low melting points

SO2, N2, PCl3 are examples

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17

Atomic Solids

A solid that contains atoms at the lattice points.

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18

Electron Sea Model

Pictures a regular array of metal atoms in a "sea" of valence electrons that are shared among the atoms in a nondirectional way and that are quite mobile in the metal crystal.

<p>Pictures a regular array of metal atoms in a "sea" of valence electrons that are shared among the atoms in a nondirectional way and that are quite mobile in the metal crystal.</p>
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19

Alloy

A substance that contains a mixture of elements and has metallic properties.

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20

Substitutional Alloy

Some of the host metal atoms are replaced by other metal atoms of similar sizes.

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21

Interstitial Alloy

Formed when some of the interstices (holes) among the closely packed metal atoms are occupied by atoms much smaller than the host atoms.

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22

metals

Zr, Ba, Pb are examples of

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23

Covalent network solids

diamond and quartz are examples of

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24

Vapor pressure

Ether>Alcohol>water in this property

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25

evaporation

H2O(l) ->H2O(g) below 100 degrees celsius

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26

deposition

change from a gas to a solid

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27

london dispersion forces

the intermolecular forces between CH4 molecules

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28

Hydrogen Bonds

The intermol. Forces between HF molecules

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29

Sublimation

The change from a solid to a gas

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30

metallic solids

Conducts as a liquid and as a solid

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