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s orbital

px orbital

py orbital

pz orbital

dxz orbital

dxy orbital

dyz orbital

dx^2-y^2 orbital

dz^2 orbital

hard acid/base
small, highly charged, non-polarizable
soft acid/base
large, highly charged, polarizable
MO diagram of hard-hard interaction
large energy gap
MO diagram of soft-soft interaction
smaller energy gap
rock salt lattice
ccp with octahedral sites filled

cesium chloride lattice
simple cubic lattice

Zinc blende lattice
cubic close packed with half of tetrahedral holes filled

Wurtzite lattice
hexagonal close packed

Fluorite lattice
ccp with all tetrahedral sites filled

ionic solids
insulators