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Exact Numbers
counted numbers
unit conversions in the same system (ex: 1 kg-1000g)
not considered when trying to figure how many sig figs should have
Measured Numbers
use measuring devices
device used → how many digits we record
thermometer (temp)
graduated cylinder (vol)
burette (vol)
scale (mass)
4 rules of 0’s in sig figs
non zero numbers are ALWAYS significant
Leading zeros are NEVER significant
Captive Zeros are ALWAYS significant
Trailing zeros are significant when there’s a decimal point
All digits in the coefficient of a scientific notation are significant
Rules for significant figures in adding + subtracting
calculated answer should have the same # of digits after decimal point as the # in the calculation with the LEAST digits after the decimal
Rules for significant figures in multiplying + dividing
calculated answer must contain the same # of SF as the # in the calculation w. the LEAST SF’s
Rules for significant figures in Averages
Apply rule of Addition for averages because counting numbers are not significant
Intensive property
only depends on the type of property but not on how much there is
ex: density…iron’s density is the same regardless of shape/size
when volume changes, mass changes proportionally
Extensive Property
depends on the amount
ex: mass, volume
how would you get the volume of an object like metal
measure the volume of water in a cylinder or other tool
measure the amount of volume after the object is put in
Subtract water w. metal - water
Accuracy/Percent Error
compare experimental value to known value (true value: provided or easily looked up)
0-100 |experimental-true|/true x 100
use rule of division
expressed as a %
precision
compare closeness of your values to one another
how repeatable are data points to one another
average deviation/average value x 1,000 (ppt: parts per thousand)
0 (little deviation) - 1,000 ( a lot of deviation)
to find deviation: density of each trial-average density
Physical property
The composition of the substance does not change in measuring either the
mass or the volume and hence the density
is temperature intensive or extensive
extensive because heating causes expansion and cooling causes contraction
if a series of liquids are places on top one another, what liquid is the most dense
the one at the bottom