Chemical Reactions: Alcohols, Ethers, Thiols, Thioethers IUPAC Naming Rules

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A collection of flashcards designed to facilitate the understanding of chemical reactions involving alcohols, ethers, thiols, and thioethers along with their IUPAC naming conventions.

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16 Terms

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IUPAC Naming Rules

A method for naming chemical compounds systematically using specific steps such as identifying the base structure, substituents, and applying rules for numbering.

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Acyclic Molecules

Molecules that do not contain a ring structure

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Cyclic Molecules

Molecules that contain a ring structure

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Substituent

An atom or group of atoms that replaces hydrogen in a hydrocarbon, altering its properties.

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Stereoisomer

Compounds with the same molecular formula but different spatial arrangements of atoms, designated by terms like cis, trans, E, and Z.

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Boiling Points

Temperature at which a liquid boils; influenced by structural factors such as chain length and the presence of hydrogen bonds.

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Solubility

The ability of a substance to dissolve in a solvent; alcohols with 4 or fewer carbon atoms are typically soluble in water.

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Markovnikov Addition

An addition reaction where the more substituted carbon atom receives more of the incoming groups, often in the context of hydration of alkenes.

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Hydration Reactions

Reactions in which water is added to a substance; often involve Markovnikov and Anti-Markovnikov addition.

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Conversion to Ethers

A chemical reaction where alcohols are dehydrated to form ethers even through intermolecular or intramolecular processes.

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Saitzev Rule

A principle stating that in elimination reactions, the more substituted double bond will be the major product.

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Alcohol Dehydration

A reaction where water is removed from an alcohol to form an alkene or ether, either intermolecularly or intramolecularly.

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Oxidation of Alcohols

A chemical reaction wherein alcohols are converted to a higher oxidation state, such as aldehydes or ketones, depending on the type of alcohol.

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Thioethers

Compounds containing a sulfur atom between two alkyl or aryl groups; also referred to as sulfides.

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Chemical Properties of Haloalkanes

Characteristics involving substitution reactions which can convert haloalkanes to alcohols, ethers, thiols, thioethers, or organometallic reagents.

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Conversion to Thioethers

The process through which thiols react with haloalkanes to produce thioethers.