[Ben] Exam 2 Alcohols Review
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Last updated 7:44 PM on 10/9/25
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61 Terms
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NABH4
weak reducing agent
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LAH
strong reducing agent
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LAH and NABH4 are associated with
reduction runs
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X=
-Cl, -OH, -OR
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LAH
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If -X = -OH, the second product is
H2O
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If -X = -OR, the second product is
ROH
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To add an R group, react with
R-Li or R-MgCl
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X=
-Cl or -OR
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H2SO4, E1
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HBr, SN1
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HI, SN2
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no rxn
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oxidation rxn
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oxidation
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oxidation
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weak oxidation rxn reagents
PCC, swern, DMP
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strong oxidation reagents
CrO3, H2SO4, K2Cr2O7, NaOCl
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TsCl
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Lucas Reagant
ZnCl2/HCl
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Rate of rxns
3rd degree > 2nd » 1st
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no rxn
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PX3 where X = Cl, Br, I [SN2]
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SOCl2
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ester formation
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h+
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ester formation mech
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protecting groups
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R-OH
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TBAF provides the
F: -
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F: - provided by
TBAF
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R-OH
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R-OTMS
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TMSCl
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F: -
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TMSF
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R-O: -
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W.V.
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R-OH
Note 
Flashcards (20)