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ch2
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superconductivity
phenomenon in which particular materials exhibit zero resistance below a particular temperature called critical temperature. (Tc)
crital temperature (Tc)
particular temperature below which superconductors exhibit superconductivity.
Applications of superconductors
Transmission wires (electricity cables)
MRI Scans (Magnetic Resonance Image)
Transition temperature
temp diff between a particular temp and critcal temp
superconductivity depends on
magnetic field and temperature
critcal field*
Minimum magnetic field required to destroy the superconductive property of a material below critical temperature (Tc).
Tuyns Law
or
Relation between critical field and critical temperature
also derive the relation when T=0K & T=Tc + graph
Hc(T)=H(0)*[1-(T/Tc)²]
Hc(T)- critcal field at temp T K
H(0)- critical field at 0K
Tc-critical temp
T-particular temp T K
![<p>H<sub>c</sub>(T)=H(0)*[1-(T/T<sub>c</sub>)²]</p><p>H<sub>c</sub>(T)- critcal field at temp T K</p><p>H(0)- critical field at 0K</p><p>T<sub>c</sub>-critical temp</p><p>T-particular temp T K</p>](https://knowt-user-attachments.s3.amazonaws.com/81c7aa06-6284-4f6c-895f-ff19356a0264.png)
Meissner Effect (draw diagram)
phenomenon in which superconductors completely expel magnetic flux lines rom the interior of the material below the critical temperature (Tc) in presence of a magnetic field.

Type 1 and Type 2 superconductors table

BCS Theory (Bardeen, Cooper, Schrieffer)
It was the first successful microscopic theory on superconductors
founded in 1957
explained:
- electron-lattice interactions
-electron-phonon interactions
-cooper pairs
-properties of cooper pairs
results:
proves the existence of energy gaps and flux quantization
Electron-phonon interaction
current passes through superconductor
electron flows towards the positive ion in the metal lattice
coulomb attraction between electron and positive ion
there is a distortion in the lattice, i.e. positive ion gets displaced from its mean position
the smaller the mass of the positive ion core the greater distortion
scattering of electrons creating electrical resistivity
Electron-lattice interaction
after the occurance of electron-phonon interaction
when another electron comes upon the distorted positive ion it also experiences coulombs’s attractive force, interaction between two electrons through lattice
due to this interaction these two electrons develop an apparent force of attraction and move in pairs
at normal temperature the apparent force of attraction between the two electrons is very small so they don’t get paired
below the transition temperature the apparent force of attraction reaches maximum value for any two electrons of equal and opposite spin
this force of attraction > the coulomb’s force of repulsion between teh two electros so they tend to move in pairs
these are called cooper pairs
cooper pairs
electrons pairs formed by the interaction between two electrons of opposite spin and momenta in the phonon field
phonons
quanta of lattice vibrations
bosons
cooper pairs have a net spin of 0 (both e- pairs have opposite spin)
due to the net spin being 0, electron pairs in superconductors are called bosons
(all cooper pairs are bosons but NOT vice versa)
properties of cooper pairs
a dense cloud of cooper pairs form a collective state and drift through cooperatively through the material
superconducting state- ordered state of conduction electrons
motion of all cooper pairs are the same- rest or drifting with identical velocity
density of cooper pairs are very high so large currents require small velocity
The small velocity and precise ordering of cooper pairs, minimize collision process
collision with the lattice is extremely rare leading to vanishing resistivity
cooper pairs smoothly sail over the lattice point without any exchange of energy resulting in infinite electrical conductivity
Applications of superconductivity
large scale superconducting devices consist of - magnets, motors, generators, cables
magnetohydrodynamic power plant (MHD) -controlled fusion, energy storage
sea and land transportation
superconducting magnet application- maglev train, levitating trains for rapid transit system
low loss transmission lines+transfomers
perform logic and store functions in computers
small size electric generators created using superconducting coils
high capacity+high speed computer chips
cryotron- fast electric switching system operation
SQUID- superconducting magnetic energy storage system