alcohols and carboxylic acids

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20 Terms

1
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what are the three ways of manufacturing ethanol
hydration of ethene, fermentation, oxidation
2
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what are the three conditions used in hydration of ethene
catalyst- phosphoric acid
temperature- 300 C
pressure- 60-70 atm
3
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what is the word equation for hydration of ethene
ethene + water -> ethanol
4
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what is the chemical equation of hydration of ethene
C2H4 +H20 -> C2H5OH
5
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is the ethanol in hydration of ethene pure or impure
pure
6
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what are the two naturally occurring raw ingredients
crude oil, water
7
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what are the conditions used in the fermentation if ethanol
catalyst- enzymes in yeast
optimum temp- 30 C
8
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what is the word equation for fermentation
glucose -> ethanol + carbon dioxide
9
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what is the chemical equation for fermentation
C6H12O6 -> 2C2H5OH +2CO2
10
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why is 30 C the optimum temp for fermentation
otherwise, enzymes denature, or reaction will be too slow if it is colder
11
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why does fermentation take place anaerobically
if oxygen were present, the yeast produces carbon dioxide and water instead of ethanol.
12
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is the ethanol produced by fermentation pure or impure
impure- use distillation to make the product purer
13
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what is the word equation for complete combustion with alcohols (ethanol)
ethanol + oxygen -> carbon dioxide + water
14
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what is the chemical equation for complete combustion of butanol
C4H0H + 6O2 -> 4Co2 + 5H2O
15
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what are the three ways alcohols can be oxidized
- complete combustion
-microbial oxidation
-heating acids with potassium dichromate in dilute sulfuric acid
16
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which carboxylic acid is produced by the microbial oxidation of propanol
propanoic acid
17
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if methanoic acid is produced by microbial oxidation which acid was a reactant
methanol
18
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what is the method for creating ethanol with potassium dichromate
in a test tube:
- add a few drops of ethanol
-potassium dichromate (K2Cr2O7)- it is orange and a strong oxidizing agent
-dilute sulfuric acid has H+ ions which are needed to allow potassium dichromate to act as an oxidizing agent
19
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what is the reaction with heating alcohols to potassium dichromate in dilute sulfuric acid
CH3CH2OH + 2(O) -> CH3COOH + H2O
20
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what is the colour change with heating alcohols to potassium dichromate in dilute sulfuric acid
orange -> green