carboxylic acid reaction with carbonates
form a salt CO2 and H2O
e.g. RCOOH + NaHCO3 → RCOONa + H2O+ CO2
e.g 2RCOOH + Na2CO3 → 2CH3COONa + H2O + CO2
esterification
alcohol reacts with carboxylic acid to produce ester and water H+ from strong acid catalyses reaction. reaction is reversable
acidic hydrolysis of an ester
reversible reaction using H+ ion from strong acidic catalyst. reflux.
ester + water → carboxylic acid + alcohol
base hydrolysis of ester
ester + OH- (from base) → carboxylate ion and alcohol. reaction is in reflux
production of NO2+ (for nitration mechanism)
HNO3 +H2SO4 → HSO4- + NO2 + + H2O
production of RC+=O
RC=OCl is a weak electrophile
AlCl3 accepts -Cl forming AlCl4
R-C+=O also formed