organic chemistry non mechanism reactions

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carboxylic acid reaction with carbonates

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carboxylic acid reaction with carbonates

form a salt CO2 and H2O

e.g. RCOOH + NaHCO3 → RCOONa + H2O+ CO2

e.g 2RCOOH + Na2CO3 → 2CH3COONa + H2O + CO2

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2

esterification

alcohol reacts with carboxylic acid to produce ester and water H+ from strong acid catalyses reaction. reaction is reversable

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3

acidic hydrolysis of an ester

reversible reaction using H+ ion from strong acidic catalyst. reflux.

ester + water → carboxylic acid + alcohol

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4

base hydrolysis of ester

ester + OH- (from base) → carboxylate ion and alcohol. reaction is in reflux

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5

production of NO2+ (for nitration mechanism)

HNO3 +H2SO4 → HSO4- + NO2 + + H2O

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6

production of RC+=O

RC=OCl is a weak electrophile

AlCl3 accepts -Cl forming AlCl4

R-C+=O also formed

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