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Free Radical Stability Trend

What is required for the formation of free radicals?
Heat
Initiation
Radical is on the right side
produces 2 radicals
propagation
produces another radical
RDS
needs a lot of activation energy
termination
radical on the left

more selective!

CL2 exception

NMS is used to
brominate allylic and benzylic
so we only get a single addition of bromine

major is most substituted alkene





diene

dienophile









allylic carbon
carbon adjacent to a C-C double bond

