Chemical analysis

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17 Terms

1
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2
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What is chromatography

technique that separates out all different compounds in a mixture

3
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what are the two phases in chromatography

stationary phase = column or paper (hydrophillic)

mobile phase = solvent (hydrophobic)

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in chromatography how do we know which spot is more polar

spot with the smaller rf value so attracted more to the stationary phase

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how do we calculate Rf value

distance moved by sample/ distance moved by solvent

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how do we know if the reaction is complete OR not complete in thin layer chromatography

complete = there is no more of the starting material

incomplete = there is still some of the starting material left

<p>complete = there is no more of the starting material </p><p>incomplete = there is still some of the starting material left</p>
7
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impurities do what to the melting point

they lower it

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what is empirical formula

what is molecular formula

formula showing simplest ratio of atoms of each element present in a compound

formula showing the Actual number of atoms of each element present in a compound

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how to work out molecular formula

empirical formula x whole number

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formula for relative abundance

total relative mass of sample / total relative abundance

<p><span><span>total relative mass of sample / total relative abundance</span></span></p>
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what is the molecular ion peak

peak on the furthest right of spectrum and highest m/v value and also represents molecular weight

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in mass spectrum the peak on the far right is the what

why is there a peak there

M+ peak

presence of isotope carbon 13 which represents 1% of carbon atoms

<p>M+ peak</p><p>presence of isotope carbon 13 which represents 1% of carbon atoms</p><p></p>
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the peak to the right of the M+ peak is the what

M+1 peak and doesnt play a role in fragmentation

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in flame tests what colours do these metals produce:

lithium

sodium

potassium

rubidium

caesium

calcium

strontium

barium

copper

red

orange

lilac

violet

blue-violet

orange-red

red

pale green

green-blue

<p>red</p><p>orange</p><p>lilac</p><p>violet</p><p>blue-violet</p><p>orange-red</p><p>red</p><p>pale green</p><p>green-blue</p>
15
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what happens inside the atom when heated

The heat of the flame excites an electron - promotes an outer
electron to a higher energy level

The excited atom then relaxes back to the ground state by
releasing light energy

<p><span><span>The heat of the flame excites an electron - promotes an outer</span></span><br><span><span>electron to a higher energy level</span></span></p><p><span><span>The excited atom then relaxes back to the ground state by</span></span><br><span><span>releasing light energy</span></span></p>
16
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in the infrared spectrum what is the fingerprint region

below 1500

<p>below 1500</p>
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what do the OH on an alcohol and OH of a carboxylic acid look like

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