IB SL Chemistry- Structure 3.2

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56 Terms

1

One

“Meth-”

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2

Two

“Eth-”

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3

Three

“Prop-”

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4

Four

“But-”

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5

Five

“Pent-”

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6

Six

“Hex-”is the prefix for six carbon atoms in organic compounds.

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7

Seven

“Hept-”

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8

Eight

“Oct-”

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9

Nine

“Non-”

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10

Ten

“Dec-”

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11

F. Group: Halogeno

Class: Halogenoalkanes, containing group 17 atoms attached to an R group.

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12

F. Group: Hydroxyl

Class: Alcohols, containing an -OH group attached to an R group.

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13

F. Group: Carbonyl

Class: Aldehydes and ketones, featuring an R group double-bonded to an oxygen atom.

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14

Aldehydes

Aldehydes: R group double-bonded to an oxygen atom + hydrogen atom.

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15

Ketones

Ketones: R group double-bonded to an oxygen atom + an R’ group.

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16

F. Group: Carboxyl

Class: Carboxylic acids, featuring an R group double-bonded to an oxygen atom and single-bonded to a hydroxyl group.

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17

F. Group: Alkoxy

Class: Ethers, characterized by an R group bonded to an oxygen atom, which is also bonded to another R' group.

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18

F. Group: Amino

Class: Primary Amines, containing an R group bonded to a nitrogen atom, which is also bonded to two hydrogen atoms.

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19

F. Group: Amido

Class: Amides, containing an R group bonded to a carbonyl group (C=O) and a nitrogen atom with two hydrogen atoms.

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20

F. Group: Ester

Class: Esters, characterized by an R group bonded to a carbonyl group (C=O) and an oxygen atom that is also bonded to another R' group.

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21

F. Group: Phenyl

Class: Aromatics, consists of a benzene ring (C6H5) attached to an R group.

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22

Catenation

The process by which many identical atoms are joined together by covalent bonds (straight-chain, branched, or cyclis structures).

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23

Functional Group

An atom/group of atoms that gives organic compounds their physical and chemical characteristics.

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24

Homologous Series

A family of compounds that can be grouped together based on similarities in their structure and reactivity (same general formula).

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25

Structural Formulas

Full/Displayed, Condensed, or Skeletal/Line.

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26

Saturated Compounds

All Carbon-Carbon bonds are single.

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27

Unsaturated Compounds

One or more double or triple Carbon-Carbon bonds.

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28

Alkyl Group

Carbon-containing groups with no other functionalities.

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29

Aliphatic

The molecules contain no aromatic rings (Alkanes and Alkenes).

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30

Alkanes

CnH2n+2, saturated, “-anes,” single bonds

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31

Alkenes

CnH2n, unsaturated, “-enes,” double bonds

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32

Alkynes

CnH2n-2, unsaturated, “-ynes,” triple bonds

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33

Halogenalkenes

CnH2n+1X, an Alkene but one H is a Halogen (X).

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34

As molar mass increases/As Carbon chain length increases…

boiling point, melting points, strength of LDFs, density, and velocity increases.

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35

Fractional Distillation

Physical separation process where crude oil is vaporized and then passed through a column to separate members of the homologous series.

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36

Substituent

Any part of an organic compound that is not part of the longest carbon chain.

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37

Branched-Chain Alkane

An Alkane with Alkyls substituents.

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38

Structural/Constitutional Isomers

Compounds that have the same molecular formula but different connectivity of the atoms.

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39

Chain Isomers

Different lengths of carbon chains.

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40

Positional Isomers

The position of the functional group changes.

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41

Primary

Carbon atom is bonded to one other Carbon atom.

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42

Secondary

Carbon atom is bonded to two other Carbon atoms.

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43

Tertiary

Carbon atom is bonded to three other Carbon atoms.

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44

Functional Group Isomers

Atoms arranged differently such that they have different functional groups.

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45

Terminal Position

In Aldehydes, when the Carbonyl group (C=O) is at the end of the carbon chain.

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46

Alkane suffix

“-ane”

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47

Alkene suffix

“-ene”

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48

Alcohol suffix

“-anol”

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49

Ketone suffix

“-one”

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50

Aldehyde suffix

“-al”

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51

When naming hydrocarbons with group 17 atoms, are the elements listed in alphabetical order? True or False?

True

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52

When choosing the locant number lineup for hydrocarbons with group 17 atoms, the most electronegative element will have the least locant number. True or False?

True

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53

Carboxyl groups suffix

“-oic acid”

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54

True or False: When naming hydrocarbons with a Carboxyl group, you do not need to assign locants to the Carboxyl group because they are always in the terminal position.

True

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55

Alkoxy suffix

“-oxy”

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56

Ester suffix

“-oate”

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