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SVT Bio Y12
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monosacharide
a single sugar unit
disacharide
two sugar units/dimer
polysacharide
many sugar units
three examples of monosacharides
glucose, fructose, galactose
3 examples of disacharides
maltose, sucrose, lactose
3 examples of polysacharides
starch, glycogen, cellulose
what is the bond joining the disacharide
glycocidic bond
what reaction forms disacharides, and polysacharides
condensation reaction
release of H20
condensation
maltose
glucose+glucose
sucrose
glucose+fructose
lactose
glucose+galactose
why does the second B-glucose have to flip when two B-glucose molecules are joined by condensation
β-glucose has its –OH group on carbon 1 (C1) pointing upward.
To form a β-1,4 glycosidic bond, the C1 of one β-glucose must link to the –OH on carbon 4 (C4) of another β-glucose.
what are the monomers of starch?
amylose and amylopectin
explain the bonds between the monomers in starch
Glycosidic bond 1-4 (linear), 1-6 branch points in amylopectin
location of starch
inside plant cells, roots, seeds
structure of starch
linear branched coiled compact structure
how does the structure of starch lead to it’s function
Long chain bonded by a- glycosidic bond alpha 1-4 giving it a coiled structure, as well as alpha 1-6 glycosidic bonds resulting in the branch structure (amylopectin)
what is the function of starch
energy storage in the cell.
what are the monomers of cellulose
B-Glucose molecules
what is the function of cellulose
protecting plant cell.
location of cellulose
Plant cell wall
What is the structure of cellulose
1-4 B-glucose ratio forming straight chains, each B-glucose is rotated 180degrees relative to previous to form straight structure creating strong H-bonds.
what are the bonds forming cellulose called
H-bonds, b-1-4 glycosidic bond
how does the structure of cellulose lead to it’s function
The B-glucose run parallel to one another and the multitude of H-Bonds create microfibril which become a part of macrofibril giving high tension and rigidity that make up the cell wall of the plant (therefore protecting it)
what are the monomers of glycogen
a-glucose
what are the bonds that make up glycogen called
1-4 glycosidic bonds, yet more 1-6 glycosidic bonds
Where is Glycogen located
Liver
What is the structure of glycogen
Contains 1-4 glycosidic bonds, yet more 1-6 glycosidic bonds which results in a highly branched structure
what would happen to the DE value if sucrose was heated with dilute HCl in a chemical reaction
the hydrolisis reaction would produce glucose and fructose (both reducing sugars) which would increase the DE value.
how does the structure of glycogen lead to it’s function
The highly branched structure is more compact than starch as a result of having more a-1-6 glycosidic bonds allows for energy to be broken down faster due to the high amount of ends that enzymes can release glucose quickly (suiting rapid energy release)
why is starch coiled (in the case of amylose)
makes molecule compact for storage of energy in the cell.
why is starch branched (in the case of amylopectin)
more ends for fast breakdown of energy/ more enzyme action allowed
starch CANNOT
dissolve in water
cross the cell membrane
polymers of glucose
can be rapidly broken down to provide glucose for respiration through hydrolisis (splitting of H20)
what is a lipid
a hydrophobic polar molecule that is soluble in non polar solvents - eg: butter, oil, waxes.
Lipid Function
stores energy
contributes to flexible membranes in the plasma membrane
long lasting energy source
retain heat under the skin through insulation.
Saturated Fatty Acid
hydrocarbon chain has only single bonds (solid)
Unsaturated Fatty Acid
C=C double bonds, at least one double bond, loses 2 Hydrogen for every double bond present (liquid).
what makes tryglicerides
3OH groups and 3 Fatty acids
what is the reaction triglycerides are created through called
dehydration synthesis
what is the waste product in the formation of triglycerides
3H20 - 1 hydrogen from each OH group, and 1 HO from each fatty acid group
what do phospholipids contain
CHONP
phospholipids
make up the cell membrane
the outside of the cell is
hydrophilic (polar)
the inside of the cell is
hydrophobic (non polar)
proteins are made up ofÂ
CHON
carbohydrates and lipids are mainly made up of
CHO (phospholipids)
3 functions of proteins:
making up enzymes, forming antibodies, building muscle
monomers of proteins
amino acids
how is a dipeptide formed
through the joining of the carboxyl and amino acids by a condensation reaction.
primary structure of proteins
a sequence of amino acids making up a polypeptide chain determining the shape of the protein with limitless ammounts of combinations.
what is the bond in the primary structure of proteins maintaining structure called
peptide bond
secondary structure of proteins
the folding or coiling of the primary structure’s polypeptide chain into shapes like a-helice and b- pleated sheets.
alpha-helices
very stable
tightly coiled spiral
how are a-helices formed?
the backbone of the polypeptide chain coils and are stabilized by hydrogen bonds
tertiary structure of proteins
folded polypeptide chain due to R group
coiled 3D shape
hydrophilic R group on outside
bonds in tertiary structures
ionic bonds
disulfide bonds
hydrogen bonds
quaternary structue
multiple polypeptide chains (2 or more)
H-bonds and R group interactions occur based on the amino acids in the proteins
bonds in quaternary structure
H - bondsÂ