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Lattice Energy
The energy released during the formation of the crystalline solid from its gaseous ions.
e.g. Na+(g) + Cl-(g) -----> NaCl(s)
Standard Enthalpy of Formation
The calculated amount of energy released when a compound is formed from its constituent elements in their natural phases.
e.g. Na(s) + (1/2)Cl2(g) → NaCl(s)
Sublimation energy
Formation of a gaseous species of a specific substance from the solid species.
e.g. Na(s) -----> Na (g)
Bond Energy
The amount of energy required to break a bond between a diatomic molecule to form a single atom.
e.g. (1/2) Cl2 (g) -->Cl (g)
Ionization Energy
The energy required remove an electron from a neutral gaseous species.
e.g. H(g) -----> H+(g) + e-
Electron Affinity
the energy given off when a neutral atom in the gas phase gains an extra electron to form a negatively charged ion.
(usually a negative number)
e.g. F(g) + e- -----> F-(g)
Born Haber Cycle
Standard Enthalpy of Formation =
(Sublimation energy + bond energy + ionization energy + electron affinity + lattice energy)