Reagents in Orgo for AlkYnes

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9 Terms

1
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NaNH3

OR

NaØ

NH3

Trans reduction

2
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H2, Lindlar’s cat.

Cis reduction

3
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H2/Pt

OR

H2

Pd/C

Full reduction from alkyne to alkane

4
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1) 2 equiv. NaNH2

1) Deprotonation

If there is no step 2, the Na+ binds to the C-

5
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Li as an ion bound to C

Analogous with Na

6
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2)

7
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LDA

???

8
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Au+

H2O

Hydration

9
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1) O3

2) H2O

(terminal C)

Ozonolysis

adds