3) Types of stereoisomers

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11 Terms

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What are enantiomers?

A chiral molecule (molecule that cannot overlap) and you make the mirror image

<p>A chiral molecule (molecule that cannot overlap) and you make the mirror image </p>
2
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When drawing enantiomers, what is an easy way?

Keep the molecule in the same exact orientation but swap ALL dashes and wedges!

3
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What is a racemic mixture?

A solution of 2 enantiomers (50-50)

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What does achiral mean?

A molecule that can be superimposed (overlapped) on its mirror image + plane of symmetry

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What can we classify as achiral?

Any object that has NOT 4 unique things bonded to a carbon

6
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What is a plane of symmetry?

A mirror plane that cuts a molecule in half, so that one half of the molecule is a reflection of the other half

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What are diastereomers?

Stereoisomers that are NOT mirror images of each other; not the mirror image and NOT the original molecule

<p>Stereoisomers that are NOT mirror images of each other; not the mirror image and NOT the original molecule</p>
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What is a Meso compound?

Has stereogenic/chiral center but is achiral; only happens if the molecule has a plane of symmetry

<p>Has stereogenic/chiral center but is achiral; only happens if the molecule has a plane of symmetry </p>
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How many stereogenic centers do Meso compounds need to get a plane of symmetry?

2 chiral centers

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When counting the total amount of stereoisomers, does identical count?

No, subtract one: 2^n -1

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Side note:

you can 10² stereogenic centers, ONE enantiomer, and tons of diastereomers