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Nonpolar bonds
When the atoms in a bond are the same element
Electrons are shared equally
Polar bonds
when two different atoms are in a bind
Electrons may not be shared equally
The bigger the electronegativity difference between the elements, the more polar the bond is
How to show polar bonds
A dipole is used to show a partial charge
δ+ means partially positive
δ- means partially negative
Arrow is used to point in the direction of the greater electron density (atom with more electronegativity)
Polar molecules
Molecules have a positive and negative end
If the molecule has a lone pair on the central atom → polar overall
If the molecule has no lone pairs and the outer atoms are different → polar overall
If the molecule has no lone pairs and all the outer atoms are the same → nonpolar overall
Intramolecular forces
the forces within a molecule
Ex: the bonds
Intermoleculular forces
the forces between any two molecules
Much weaker than covalent bonds
London forces of attraction
(van der wall forces)
Electrons may create a temporary dipole (partial charge) on the atom due to constant movement
Weakest of all forces
Found between all molecules (polar and nonpolar)
Dipole-Dipole force of attraction
Found in addition to London forces in molecules that are polar (already polar)
Negative dipole attracts to positive
Hydrogen bonding
Occurs in molecules that have an H bonded to an F, O, or N → H needs to be directly attached to either F, O or N
Attraction between dipoles (Negative dipole attracts to positive)