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Moist Air
Combination of dry air and water
Mixing Ratio
(w) mass vapor/mass dry air
Total Water Mixing Ratio
(wT) (mass vapor + liquid + ice)/mass dry air
Liquid Water Mixing Ratio
(wL) mass liquid/mass dry air
Ice Mixing Ratio
(wI) mass ice/mass dry air
Specific Humidity
(q) mass vapor/mass total (air)
Relationship between specific humidity and mixing ratio
q ≈ w
Relative Humidity
Proximity to saturation
RH = e/es
Bergeron Process
esi < esl
Atmosphere can be saturated for ice but not for liquid
Snow grows at the expense of liquid water
esi < –40°C
esl > 0°C
Pseudoadiabatic
Heat stays in parcel but condensed water precipitates out; irreversible and entropy not conserved
Adiabatic
Heat and water mass remain in parcel; reversible and entropy conserved
Why use Tv
Adjust parcels to be dry so they follow dry adiabatic processes
The Temperature Framework
TLCL < Td < Twp < Tw < T < Tv < Tei < Tep
LCL Temperature
(TLCL) temperature of a parcel, lifted adiabatically, at the LCL
Dry adiabatic expansion
Coolest temperature
Dew Point
(Td) temperature at which air is saturated
Isobaric cooling
Pseudoadiabatic Wet Bulb Temperature
(Twp) temperature of parcel lowered to any level pseudoadiabatically
Pseudoadiabatic descent
Wet Bulb Temperature
(Tw) temperature of parcel after evaporative cooling until reaching saturation
Isobaric, adiabatic evaporative cooling
Temperature
dry-bulb temperature
Virtual Temperature
(Tv) equivalent temperature of air if it was dry (at same pressure and density)
“adjusted temperature” to compensate for moisture
Isobaric Equivalent Temperature
(Tei) equivalent temperature if all vapor condensed out of parcel
Isobaric, adiabatic heat release
Opposite of wet bulb
Pseudoadiabatic Equivalent Temperature
(Tep) temperature after all vapor condensed and removed from parcel (precipitated)
Isobaric pseudoadiabatic latent heat release
Potential Temperature Framework
θwp < θ ≈ θm < θv < θei < θep
Pseudoadiabatic Wet Bulb Potential Temperature
(θwp) temperature if parcel lowered to 1000mb following moist adiabat
Potential Temperature
(θ) temperature if parcel lowered to 1000mb following dry adiabat
Moist Air Potential Temperature
(θm) potential temperature adjusted for moist air
Virtual Potential Temperature
(θv) potential temperature calculated using virtual temp
accounts for moisture already in parcel
Equivalent Isobaric Potential Temperature
(θei) temperature after water condensed from parcel, then isobarically lowered to 1000mb
Equivalent Potential Temperature
(θe) temperature after water condensed from parcel adiabatically, then adiabatically lowered to 1000mb
reversible process
Pseudoadiabatic Potential Temperature
(θep) temperature after water condensed from parcel psuedoadiabatically, then lowered to 1000mb
plotted on skew-T diagrams
Isobaric Adiabatic Cooling
Liquid water will evaporate until saturation or no more liquid left
Saturation via Adiabatic Ascent
mass of vapor conserved (follow line of constant mixing ratio)
for atmospheric temps T < 1550K, e↓ slower than es↓, so saturation possible
Γdew
Dew point lapse rate ≈ 1.8 K/km
Assumptions of Vertical Motion
Hydrostatic equilibrium (background)
Parcel doesn’t mix with surroundings
Parcel doesn’t disturb surroundings
Parcel follows adiabatic process
Pressure of parcel = pressure of environment (at a given level)
Static Stability DEs: Stable
parcel cooling faster than environment (Γv’ > Γv)
parcel will oscillate with nudge—sin function (Brunt-Vaisala Frequency)
Static Stability DEs: Unstable
parcel cooling slower than environment (Γv’ < Γv)
parcel will exponentially accelerate with nudge—exponential function
Static Stability DEs: Neutral
parcel cooling equal to environment (Γv’ = Γv)
parcel will not accelerate—linear function
Stability of Unsaturated Parcels
Use Tv to be able to follow DALR
Stable: Γv < Γd
Neutral: Γv = Γd
Unstable: Γv > Γd
Stability of Saturated Parcels
Stable: Γv < Γs
Neutral: Γv = Γs
Unstable: Γv > Γs
Conditional and Absolute Stability
Absolutely Stable: Γv < Γs
Conditionally Unstable: Γs < Γv < Γd
more humid places, more unstable
Stability using θv with height
Stable: θv ↑
Neutral: θv —
Unstable: θv ↓
Stability Using θep with Height
Stable: θep ↑
Neutral: θep—
Unstable: θep ↓