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what is starch
complex carbohydrate (polysaccharide) made of thousands of glucose molecules linked by glycosidic bonds
function of starch in plants
to keep energy stored in seeds/roots for growth
function of starches in food
thickening, gelling, energy source
major sources in cereal grains
corn, wheat, rice, oats
major sources in roots
potatoes and tapioca
major sources in legumes
beans and peas
monomer
single unit of glucose
amylose
linear, forms gels
amylopectins
branched, cannot form gels
where are starch granules stored?
leucoplasts
what do starch granules contain
amylose and amylopectin
maltese cross
seen under polarized light due to crystalline (amylose) and amorphous (amylopectin) regions
starch gelatinization
process when starch granules absorb water, swell, and thicken when heated
cold water phase (Step 1)
dissolves in cold water and contains water-soluble nutrients/compounds
heating phase (step 2)
water enters granule (first amorphous then crystalline), hydrogen bonds break and granules swell, amylose leaks out and paste thickens
3rd step
thick, opaque sol
when theres higher amylose theres a what?
higher gelatinization temp.
when does gel formation (cooling process) happen after
gelatinization
what molecules realign
amylose
cereal starches have a high…
amylose, forms gels
root and waxy starches have a high…
amylopectin and no gels are formed
retrogradation
crystallization of amylose/amylopectin during storage
syneresis
loss of water from a starch gel
whats an example of retrogradation?
bread staling
what should you mix starch with to prevent clumps in fat/oils
gravies, sauces
what should you mix starch with to prevent clumps in sugar
puddings, desserts
what should you mix starch with to prevent clumps in cold water
fats and sf products
moderate stirring=
smooth texture
excess stirring=
granules burst (thinner product)
what happens to starch with acids
breaks starch (thinner)
what happens to starch with sugar
competes for water (thinner)
what happens to starch with proteins
coats granules, delays swelling, weaker gel
pregelatinized starch modification
precooked and dried
pregelatinized starch purpose/used in
thickens in cold liquids, pudding
cross linked starch modification
chemically linked molecules
cross linked starch purpose/used in
stable under acid and heat, pizza/BBQ sauce
substituted starch modification
added chemical groups
substituted starch purpose/used in
prevents syneresis in frozen foods
acid modified starch process
heated with dilute acid
acid modified starch purpose/used in
forms strong gels when cooling, gummy candies